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Syntheses and structural characterization of new trans-bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato] nickel(II), the pyridine derivative thereof, and bis-{bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]cobalt(II)} complexes

Saglam, Ertugrul Gazi; Dal, Hakan; Mougang-Soume, Berline; Hokelek, Tuncer


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/5669</identifier>
  <creators>
    <creator>
      <creatorName>Saglam, Ertugrul Gazi</creatorName>
      <givenName>Ertugrul Gazi</givenName>
      <familyName>Saglam</familyName>
      <affiliation>Bozok Univ, Dept Chem, TR-66900 Yozgat, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dal, Hakan</creatorName>
      <givenName>Hakan</givenName>
      <familyName>Dal</familyName>
      <affiliation>Anadolu Univ, Open Educ Fac, Dept Med Serv &amp; Tech, TR-26470 Tepebasi, Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Mougang-Soume, Berline</creatorName>
      <givenName>Berline</givenName>
      <familyName>Mougang-Soume</familyName>
      <affiliation>Univ Montreal, Dept Chem, Montreal, PQ, Canada</affiliation>
    </creator>
    <creator>
      <creatorName>Hokelek, Tuncer</creatorName>
      <givenName>Tuncer</givenName>
      <familyName>Hokelek</familyName>
      <affiliation>Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Syntheses And Structural Characterization Of New Trans-Bis-[N-Butyl-(P-Methoxyphenyl) Dithiophosphinato] Nickel(Ii), The Pyridine Derivative Thereof, And Bis-{Bis-[N-Butyl-(P-Methoxyphenyl) Dithiophosphinato]Cobalt(Ii)} Complexes</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/5669</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molstruc.2019.127222</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Three new metal complexes of ammonium n-butyl-(p-methoxyphenyl) dithiophosphinate (NH4L) were synthesized. NH4L was treated with NiCl2 center dot 6H(2)O and CoCl2 center dot 6H(2)O in ethanol to obtain a new trans-bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]nickel(II) and bis-{bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]cobalt(II)} complexes, ([Ni(L)(2)] and [Co-2(mu-L)(2)(L)(2)], respectively). Square-planar nickel(II) complex was furthermore reacted with excess pyridine (Py) and the octahedral {bis-pyridine-bis-[n-butyl-(p-methoxyphenyl)]}nikel(II) complex, ([Ni(L)(2)(Py)(2)]), was obtained.</description>
  </descriptions>
</resource>
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