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Carbon nanofiber/poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) binder-free composite redox-active electrode for electrochemical energy storage applications

Yigit, Deniz; Soysal, Furkan; Gungor, Tugba; Cicek, Burhanettin; Gullu, Mustafa


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Yigit, Deniz</dc:creator>
  <dc:creator>Soysal, Furkan</dc:creator>
  <dc:creator>Gungor, Tugba</dc:creator>
  <dc:creator>Cicek, Burhanettin</dc:creator>
  <dc:creator>Gullu, Mustafa</dc:creator>
  <dc:date>2017-01-01</dc:date>
  <dc:description>We report the preparation and supercapacitive properties of a novel composite electrode material based on carbon nanofiber (CNF) and poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) (PTDTD) for electrochemical energy storage applications. The CNF/PTDTD composite electrode was directly prepared by electrodeposition of PTDTD on the CNF coated substrate without any binder or conductive additives. The symmetric solid-state supercapacitor device was assembled by using these CNF/PTDTD composite electrodes. In addition, CNF/CNF and CNF/poly(3,4-ethylenedioxythiophene) (PEDOT) symmetric supercapacitor devices were also fabricated to make a detailed performance comparison. The electrochemical characteristics of all supercapacitor devices were comprehensively evaluated by CV, GCD and EIS measurements. The CNF/PTDTD composite electrodes delivered a maximum specific capacitance of 332 F g(-1), energy density of 166 W h k g(-1), power density of 4.9 kW kg(-1) and an excellent cycling stability with 89% capacitance retention after 12 500 cycles at 2 mA cm(-2) current density while CNF/PEDOT electrodes were able to reach a specific capacitance of 254 F g(-1), energy density of 128.8 W h kg(-1) and power density of 5.45 kW kg(-1) in those supercapacitor devices. These results confirmed that PTDTD has significant potential to be a good alternative redox-active material and CNF/PTDTD composite structure is a promising candidate for supercapacitor applications.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/50933</dc:identifier>
  <dc:identifier>oai:zenodo.org:50933</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>RSC ADVANCES 7(66) 41419-41428</dc:source>
  <dc:title>Carbon nanofiber/poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) binder-free composite redox-active electrode for electrochemical energy storage applications</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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