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Carbon nanofiber/poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) binder-free composite redox-active electrode for electrochemical energy storage applications

Yigit, Deniz; Soysal, Furkan; Gungor, Tugba; Cicek, Burhanettin; Gullu, Mustafa


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{
  "DOI": "10.1039/c7ra05545e", 
  "abstract": "We report the preparation and supercapacitive properties of a novel composite electrode material based on carbon nanofiber (CNF) and poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) (PTDTD) for electrochemical energy storage applications. The CNF/PTDTD composite electrode was directly prepared by electrodeposition of PTDTD on the CNF coated substrate without any binder or conductive additives. The symmetric solid-state supercapacitor device was assembled by using these CNF/PTDTD composite electrodes. In addition, CNF/CNF and CNF/poly(3,4-ethylenedioxythiophene) (PEDOT) symmetric supercapacitor devices were also fabricated to make a detailed performance comparison. The electrochemical characteristics of all supercapacitor devices were comprehensively evaluated by CV, GCD and EIS measurements. The CNF/PTDTD composite electrodes delivered a maximum specific capacitance of 332 F g(-1), energy density of 166 W h k g(-1), power density of 4.9 kW kg(-1) and an excellent cycling stability with 89% capacitance retention after 12 500 cycles at 2 mA cm(-2) current density while CNF/PEDOT electrodes were able to reach a specific capacitance of 254 F g(-1), energy density of 128.8 W h kg(-1) and power density of 5.45 kW kg(-1) in those supercapacitor devices. These results confirmed that PTDTD has significant potential to be a good alternative redox-active material and CNF/PTDTD composite structure is a promising candidate for supercapacitor applications.", 
  "author": [
    {
      "family": "Yigit", 
      "given": " Deniz"
    }, 
    {
      "family": "Soysal", 
      "given": " Furkan"
    }, 
    {
      "family": "Gungor", 
      "given": " Tugba"
    }, 
    {
      "family": "Cicek", 
      "given": " Burhanettin"
    }, 
    {
      "family": "Gullu", 
      "given": " Mustafa"
    }
  ], 
  "container_title": "RSC ADVANCES", 
  "id": "50933", 
  "issue": "66", 
  "issued": {
    "date-parts": [
      [
        2017, 
        1, 
        1
      ]
    ]
  }, 
  "page": "41419-41428", 
  "title": "Carbon nanofiber/poly(tetrahydro[1,4] dioxino[2,3-b] thieno[3,4-e][1,4] dioxine) binder-free composite redox-active electrode for electrochemical energy storage applications", 
  "type": "article-journal", 
  "volume": "7"
}
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