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Short Naphthalene Organophosphonate Linkers to Microporous Frameworks

Bulut, Aysun; Zorlu, Yunus; Worle, Michael; Cetinkaya, Ahmet; Kurt, Huseyin; Tam, Benjamin; Yazaydin, A. Ozgur; Beckmann, Jens; Yuecesan, Guendog


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        "name": "Bulut, Aysun"
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      {
        "affiliation": "Gebze Tech Univ, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
        "name": "Zorlu, Yunus"
      }, 
      {
        "affiliation": "ETH, Inorgan Chem Lab, HCI H103 Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland", 
        "name": "Worle, Michael"
      }, 
      {
        "affiliation": "Yildiz Tech Univ, Dept Bioengn, Istanbul, Turkey", 
        "name": "Cetinkaya, Ahmet"
      }, 
      {
        "affiliation": "Istanbul Medeniyet Univ, Dept Engn Phys, Istanbul, Turkey", 
        "name": "Kurt, Huseyin"
      }, 
      {
        "affiliation": "UCL, Dept Chem Engn, London WC1E 7JE, England", 
        "name": "Tam, Benjamin"
      }, 
      {
        "affiliation": "UCL, Dept Chem Engn, London WC1E 7JE, England", 
        "name": "Yazaydin, A. Ozgur"
      }, 
      {
        "affiliation": "Univ Bremen, Inst Anorgan Chem & Kristallog, Leobener Str, D-28359 Bremen, Germany", 
        "name": "Beckmann, Jens"
      }, 
      {
        "affiliation": "Tech Univ Berlin, Dept Food Chem & Toxicol, Gustav Meyer Allee 25, D-13355 Berlin, Germany", 
        "name": "Yuecesan, Guendog"
      }
    ], 
    "description": "We report two novel 3D porous metal-organophosphonate metal organic frameworks (MOFs) [{Cu(4,4'-bpy)(0.5)(1,4-NDPA-H-2)] (1), [{Cu-2(4,4'-bpy)(0.5)}(1,4-NDPA)] (2) and a non-porous [{Cu(4,4'-bpy)}(2,6-NDPA-H-2)] (3) constructed using the structurally rigid 1,4-naphthalenediphosphonic acid (1,4-NDPA-H-4) and 2,6-naphthalenediphosphonic acid (2,6-NDPA-H-4). 1 and 2 exhibit high surface areas obtained using the structurally rigid and short aromatic organophosphonate linkers with copper. The compound 1 has been further analyzed by TGA and Quantum Design PPMS vibrating sample magnetometer.", 
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    "title": "Short Naphthalene Organophosphonate Linkers to Microporous Frameworks"
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