Yayınlanmış 1 Ocak 2017
| Sürüm v1
Dergi makalesi
Açık
Short Naphthalene Organophosphonate Linkers to Microporous Frameworks
Oluşturanlar
- 1. Gebze Tech Univ, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey
- 2. ETH, Inorgan Chem Lab, HCI H103 Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland
- 3. Yildiz Tech Univ, Dept Bioengn, Istanbul, Turkey
- 4. Istanbul Medeniyet Univ, Dept Engn Phys, Istanbul, Turkey
- 5. UCL, Dept Chem Engn, London WC1E 7JE, England
- 6. Univ Bremen, Inst Anorgan Chem & Kristallog, Leobener Str, D-28359 Bremen, Germany
- 7. Tech Univ Berlin, Dept Food Chem & Toxicol, Gustav Meyer Allee 25, D-13355 Berlin, Germany
Açıklama
We report two novel 3D porous metal-organophosphonate metal organic frameworks (MOFs) [{Cu(4,4'-bpy)(0.5)(1,4-NDPA-H-2)] (1), [{Cu-2(4,4'-bpy)(0.5)}(1,4-NDPA)] (2) and a non-porous [{Cu(4,4'-bpy)}(2,6-NDPA-H-2)] (3) constructed using the structurally rigid 1,4-naphthalenediphosphonic acid (1,4-NDPA-H-4) and 2,6-naphthalenediphosphonic acid (2,6-NDPA-H-4). 1 and 2 exhibit high surface areas obtained using the structurally rigid and short aromatic organophosphonate linkers with copper. The compound 1 has been further analyzed by TGA and Quantum Design PPMS vibrating sample magnetometer.
Dosyalar
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Dosyalar
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