1 Ocak 2017 Dergi makalesi Açık Erişim

Doyranli, Ceylan; Colak, Betul; Lacinel, Gozde; Can, Mustafa; Koyuncu, Fatma Baycan; Koyuncu, Sermet

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        "affiliation": "Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, TR-17020 Canakkale, Turkey", 
        "name": "Doyranli, Ceylan"
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      {
        "affiliation": "Canakkale Onsekiz Mart Univ, Dept Energy Resources & Management, TR-17020 Canakkale, Turkey", 
        "name": "Colak, Betul"
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      {
        "affiliation": "Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, TR-17020 Canakkale, Turkey", 
        "name": "Lacinel, Gozde"
      }, 
      {
        "affiliation": "Izmir Katip Celebi Univ, Fac Engn, Dept Engn Sci, TR-35620 Izmir, Turkey", 
        "name": "Can, Mustafa"
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      {
        "name": "Koyuncu, Fatma Baycan"
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    "description": "In this work, phenanthrene centered donor-acceptor monomer; 5,10-bis(4-hexyl-2-thienyl)phenantro [9,10-c][1,2,5]thiodiazole; MES16 was synthesized and then its electrochromic application of corresponding polymer was carried out. 4,7-di(thiophen-2-yl)-2,1,3-benzothiadiazole (TST) was also synthesized as a standard molecule to determine the effect of the planar phenanthrene center on electrochromic performance. Electrochemical properties were elucidated by cyclic voltammetry and then HOMO-LUMO band gaps were calculated by using their oxidation and reduction onset potentials. Finally, electrochromic properties of poly-(MES16) and poly-(TST) were investigated via spectro-electrochemical measurements. DFT calculations exhibit that poly-(MES16) has a high planarity and an intramolecular charge transfer from the polymer backbone-donor to thiadiazole-acceptor subunit. Because of high solid state it it interactions of the poly-(MES16), a good quality film was obtained corresponding to self assembly property planar phenantrene center. Owing to this property, electrochromic performance of poly-(MES16) such as response time, stability and Delta T% were better than the standard poly-(TST). (C) 2016 Elsevier Ltd. All rights reserved.", 
    "doi": "10.1016/j.polymer.2016.12.016", 
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    "journal": {
      "pages": "423-431", 
      "title": "POLYMER", 
      "volume": "108"
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    "publication_date": "2017-01-01", 
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    "title": "Effect of the planar center moiety for a donor-acceptor polymeric electrochrome"
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