1 Ocak 2017 Dergi makalesi Açık Erişim

Doyranli, Ceylan; Colak, Betul; Lacinel, Gozde; Can, Mustafa; Koyuncu, Fatma Baycan; Koyuncu, Sermet

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/45663</identifier>
  <creators>
    <creator>
      <creatorName>Doyranli, Ceylan</creatorName>
      <givenName>Ceylan</givenName>
      <familyName>Doyranli</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Colak, Betul</creatorName>
      <givenName>Betul</givenName>
      <familyName>Colak</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Dept Energy Resources &amp; Management, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Lacinel, Gozde</creatorName>
      <givenName>Gozde</givenName>
      <familyName>Lacinel</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Can, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Can</familyName>
      <affiliation>Izmir Katip Celebi Univ, Fac Engn, Dept Engn Sci, TR-35620 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Koyuncu, Fatma Baycan</creatorName>
      <givenName>Fatma Baycan</givenName>
      <familyName>Koyuncu</familyName>
    </creator>
    <creator>
      <creatorName>Koyuncu, Sermet</creatorName>
      <givenName>Sermet</givenName>
      <familyName>Koyuncu</familyName>
    </creator>
  </creators>
  <titles>
    <title>Effect Of The Planar Center Moiety For A Donor-Acceptor Polymeric Electrochrome</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/45663</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.polymer.2016.12.016</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this work, phenanthrene centered donor-acceptor monomer; 5,10-bis(4-hexyl-2-thienyl)phenantro [9,10-c][1,2,5]thiodiazole; MES16 was synthesized and then its electrochromic application of corresponding polymer was carried out. 4,7-di(thiophen-2-yl)-2,1,3-benzothiadiazole (TST) was also synthesized as a standard molecule to determine the effect of the planar phenanthrene center on electrochromic performance. Electrochemical properties were elucidated by cyclic voltammetry and then HOMO-LUMO band gaps were calculated by using their oxidation and reduction onset potentials. Finally, electrochromic properties of poly-(MES16) and poly-(TST) were investigated via spectro-electrochemical measurements. DFT calculations exhibit that poly-(MES16) has a high planarity and an intramolecular charge transfer from the polymer backbone-donor to thiadiazole-acceptor subunit. Because of high solid state it it interactions of the poly-(MES16), a good quality film was obtained corresponding to self assembly property planar phenantrene center. Owing to this property, electrochromic performance of poly-(MES16) such as response time, stability and Delta T% were better than the standard poly-(TST). (C) 2016 Elsevier Ltd. All rights reserved.</description>
  </descriptions>
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