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Triphenylamine-based allylidenemalononitrile chromophores: synthesis, and photophysical and second-order nonlinear optical properties

Catal, Emine; Keles, Ergin; Seferoglu, Nurgul; Achelle, Sylvain; Barsella, Alberto; le Guen, Francoise Robin; Seferoglu, Zeynel


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        "affiliation": "Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey", 
        "name": "Catal, Emine"
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      {
        "affiliation": "Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey", 
        "name": "Keles, Ergin"
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      {
        "affiliation": "Gazi Univ, Inst Sci & Technol, Adv Technol Dept, Ankara, Turkey", 
        "name": "Seferoglu, Nurgul"
      }, 
      {
        "affiliation": "Univ Rennes, CNRS, Inst Sci Chim Rennes, UMR6226, F-35000 Rennes, France", 
        "name": "Achelle, Sylvain"
      }, 
      {
        "affiliation": "Univ Strasbourg, IPCMS, UMR 7504, Dept Opt Ultrarapide & Nanophoton,CNRS, 23 Rue Loess,BP 43, F-67034 Strasbourg 2, France", 
        "name": "Barsella, Alberto"
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        "affiliation": "Univ Rennes, CNRS, Inst Sci Chim Rennes, UMR6226, F-35000 Rennes, France", 
        "name": "le Guen, Francoise Robin"
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      {
        "affiliation": "Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey", 
        "name": "Seferoglu, Zeynel"
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    ], 
    "description": "A series of chromophores based on a mono-, di- or tri-substituted triphenylamine core and allylidenemalononitrile fragments has been designed. The linear and second order nonlinear optical properties as well as thermal stability of the chromophores have been studied experimentally. Structure-property relationships, in terms of the branching effect on the triphenylamine core and the influence of the aniline/coumarin part on the photophysical properties and NLO response, have been highlighted. The experimental results have been rationalized by theoretical calculations.", 
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