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Triphenylamine-based allylidenemalononitrile chromophores: synthesis, and photophysical and second-order nonlinear optical properties

Catal, Emine; Keles, Ergin; Seferoglu, Nurgul; Achelle, Sylvain; Barsella, Alberto; le Guen, Francoise Robin; Seferoglu, Zeynel


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/34967</identifier>
  <creators>
    <creator>
      <creatorName>Catal, Emine</creatorName>
      <givenName>Emine</givenName>
      <familyName>Catal</familyName>
      <affiliation>Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Keles, Ergin</creatorName>
      <givenName>Ergin</givenName>
      <familyName>Keles</familyName>
      <affiliation>Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Seferoglu, Nurgul</creatorName>
      <givenName>Nurgul</givenName>
      <familyName>Seferoglu</familyName>
      <affiliation>Gazi Univ, Inst Sci &amp; Technol, Adv Technol Dept, Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Achelle, Sylvain</creatorName>
      <givenName>Sylvain</givenName>
      <familyName>Achelle</familyName>
      <affiliation>Univ Rennes, CNRS, Inst Sci Chim Rennes, UMR6226, F-35000 Rennes, France</affiliation>
    </creator>
    <creator>
      <creatorName>Barsella, Alberto</creatorName>
      <givenName>Alberto</givenName>
      <familyName>Barsella</familyName>
      <affiliation>Univ Strasbourg, IPCMS, UMR 7504, Dept Opt Ultrarapide &amp; Nanophoton,CNRS, 23 Rue Loess,BP 43, F-67034 Strasbourg 2, France</affiliation>
    </creator>
    <creator>
      <creatorName>le Guen, Francoise Robin</creatorName>
      <givenName>Francoise Robin</givenName>
      <familyName>le Guen</familyName>
      <affiliation>Univ Rennes, CNRS, Inst Sci Chim Rennes, UMR6226, F-35000 Rennes, France</affiliation>
    </creator>
    <creator>
      <creatorName>Seferoglu, Zeynel</creatorName>
      <givenName>Zeynel</givenName>
      <familyName>Seferoglu</familyName>
      <affiliation>Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Triphenylamine-Based Allylidenemalononitrile Chromophores: Synthesis, And Photophysical And Second-Order Nonlinear Optical Properties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/34967</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1039/c8nj02794c</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A series of chromophores based on a mono-, di- or tri-substituted triphenylamine core and allylidenemalononitrile fragments has been designed. The linear and second order nonlinear optical properties as well as thermal stability of the chromophores have been studied experimentally. Structure-property relationships, in terms of the branching effect on the triphenylamine core and the influence of the aniline/coumarin part on the photophysical properties and NLO response, have been highlighted. The experimental results have been rationalized by theoretical calculations.</description>
  </descriptions>
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