1 Ocak 2018 Dergi makalesi Açık Erişim

Khan, Rasool; Tavman, Aydin; Gurbuz, Demet; Arfan, Mohammad; Cinarli, Adem

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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Khan, Rasool</dc:creator>
  <dc:creator>Tavman, Aydin</dc:creator>
  <dc:creator>Gurbuz, Demet</dc:creator>
  <dc:creator>Arfan, Mohammad</dc:creator>
  <dc:creator>Cinarli, Adem</dc:creator>
  <dc:date>2018-01-01</dc:date>
  <dc:description>N-(2-1{[(2E)-2-(2-hydroxybenzylidene)hydrazinyl]carbonyl}phenyli)benzamide (HL) and its Co(II), Fe(III), Cu(II) and Zn(II) perchlorate complexes were synthesized. The structures of HL and its complexes were confirmed on the basis of elemental analysis and FT-IR, FT-Raman, H-1-NMR spectra. TGA, magnetic moment and molar conductivity measurements were carried out for the complexes. In addition, the crystal structure of HL was determined by X-ray diffraction at room temperature. It crystallizes in the monoclinic, space group C2/c and Z=4. HL has an interesting structure due to the presence of two intramolecular hydrogen bonds. It behaves as a bidentate ligand through the C=N nitrogen and OH oxygen atoms in its chelate complexes that they have 1:2 M:L (metal:ligand) ratio. The Fe(III), Cu(II) and Zn(II) complexes, [Fe(HL)(L)(H2O)(2)](ClO4)(2), [Cu(HL)(2)](ClO4)(2 center dot)3H(2)O, [Zn(HL)(2)](ClO4)(2)center dot H2O are 2:1 electrolytes whereas the Co(II) complex, [Co(HL)(L)(H2O)]ClO4 center dot H2O, is 1:1 electrolyte according to the molar conductivity data.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/30735</dc:identifier>
  <dc:identifier>oai:zenodo.org:30735</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA 32(1) 111-124</dc:source>
  <dc:title>SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF N-(2-{[(2E)-2-(2-HYDROXYBENZYLIDENE)HYDRAZINYLI CARBONYL}-PHENYL)BENZAMIDE (HL) AND ITS Co(II), Fe(III), Cu(II) AND Zn(II) COMPLEXES. X-RAY CRYSTAL STRUCTURE OF HL</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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