1 Ocak 2018 Dergi makalesi Açık Erişim

Khan, Rasool; Tavman, Aydin; Gurbuz, Demet; Arfan, Mohammad; Cinarli, Adem

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/30735</identifier>
  <creators>
    <creator>
      <creatorName>Khan, Rasool</creatorName>
      <givenName>Rasool</givenName>
      <familyName>Khan</familyName>
      <affiliation>Univ Peshawar, Inst Chem Sci, Peshawar 25120, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Tavman, Aydin</creatorName>
      <givenName>Aydin</givenName>
      <familyName>Tavman</familyName>
      <affiliation>Istanbul Univ, Fac Engn, Chem Dept, TR-34320 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gurbuz, Demet</creatorName>
      <givenName>Demet</givenName>
      <familyName>Gurbuz</familyName>
      <affiliation>Istanbul Univ, Fac Engn, Chem Dept, TR-34320 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Arfan, Mohammad</creatorName>
      <givenName>Mohammad</givenName>
      <familyName>Arfan</familyName>
      <affiliation>Univ Karachi, ICCBS, HEJ Res Inst Chem, Karachi 75270, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Cinarli, Adem</creatorName>
      <givenName>Adem</givenName>
      <familyName>Cinarli</familyName>
      <affiliation>Istanbul Univ, Fac Engn, Chem Dept, TR-34320 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Structural Characterization Of N-(2-{[(2E)-2-(2-Hydroxybenzylidene)Hydrazinyli Carbonyl}-Phenyl)Benzamide (Hl) And Its Co(Ii), Fe(Iii), Cu(Ii) And Zn(Ii) Complexes. X-Ray Crystal Structure Of Hl</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/30735</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.4314/bcse.v32i1.10</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">N-(2-1{[(2E)-2-(2-hydroxybenzylidene)hydrazinyl]carbonyl}phenyli)benzamide (HL) and its Co(II), Fe(III), Cu(II) and Zn(II) perchlorate complexes were synthesized. The structures of HL and its complexes were confirmed on the basis of elemental analysis and FT-IR, FT-Raman, H-1-NMR spectra. TGA, magnetic moment and molar conductivity measurements were carried out for the complexes. In addition, the crystal structure of HL was determined by X-ray diffraction at room temperature. It crystallizes in the monoclinic, space group C2/c and Z=4. HL has an interesting structure due to the presence of two intramolecular hydrogen bonds. It behaves as a bidentate ligand through the C=N nitrogen and OH oxygen atoms in its chelate complexes that they have 1:2 M:L (metal:ligand) ratio. The Fe(III), Cu(II) and Zn(II) complexes, [Fe(HL)(L)(H2O)(2)](ClO4)(2), [Cu(HL)(2)](ClO4)(2 center dot)3H(2)O, [Zn(HL)(2)](ClO4)(2)center dot H2O are 2:1 electrolytes whereas the Co(II) complex, [Co(HL)(L)(H2O)]ClO4 center dot H2O, is 1:1 electrolyte according to the molar conductivity data.</description>
  </descriptions>
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