1 Ocak 2018 Dergi makalesi Açık Erişim

Altan, Orhan; Yilmaz, Mustafa Kemal

Dublin Core

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  <dc:creator>Altan, Orhan</dc:creator>
  <dc:creator>Yilmaz, Mustafa Kemal</dc:creator>
  <dc:date>2018-01-01</dc:date>
  <dc:description>New phosphine-amino-alcohol tridentate ligands (3a-c) and six new ruthenium complexes (4a-c and 5a-c) were synthesized and characterized. Catalytic activities of the metal complexes were tested on aryl alkyl ketones. All of the substrates were converted to related sec-alcohols in excellent yields (up to 99%), but enantioselectivities were insufficient (up to 40% ee). Despite the catalytic performance of 5a-c complexes can be considered as better than 4a-c, actually the catalytic activity of the complexes has been differed according to substrate. The ketones with less positive carbonyl carbons tend to give S-configuration with 5a-c and R-configuration with 4a-c. The catalytic performance of the complexes was rationalized by means of DFT calculations. (C) 2018 Elsevier B.V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/28623</dc:identifier>
  <dc:identifier>oai:zenodo.org:28623</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF ORGANOMETALLIC CHEMISTRY 861 252-262</dc:source>
  <dc:title>New phosphine-amino-alcohol tridentate ligands for ruthenium catalyzed asymmetric transfer hydrogenation of ketones</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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