1 Ocak 2018 Dergi makalesi Açık Erişim

Altan, Orhan; Yilmaz, Mustafa Kemal

Citation Style Language JSON

{
  "DOI": "10.1016/j.jorganchem.2018.02.046", 
  "abstract": "New phosphine-amino-alcohol tridentate ligands (3a-c) and six new ruthenium complexes (4a-c and 5a-c) were synthesized and characterized. Catalytic activities of the metal complexes were tested on aryl alkyl ketones. All of the substrates were converted to related sec-alcohols in excellent yields (up to 99%), but enantioselectivities were insufficient (up to 40% ee). Despite the catalytic performance of 5a-c complexes can be considered as better than 4a-c, actually the catalytic activity of the complexes has been differed according to substrate. The ketones with less positive carbonyl carbons tend to give S-configuration with 5a-c and R-configuration with 4a-c. The catalytic performance of the complexes was rationalized by means of DFT calculations. (C) 2018 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Altan", 
      "given": " Orhan"
    }, 
    {
      "family": "Yilmaz", 
      "given": " Mustafa Kemal"
    }
  ], 
  "container_title": "JOURNAL OF ORGANOMETALLIC CHEMISTRY", 
  "id": "28623", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "page": "252-262", 
  "title": "New phosphine-amino-alcohol tridentate ligands for ruthenium catalyzed asymmetric transfer hydrogenation of ketones", 
  "type": "article-journal", 
  "volume": "861"
}