1 Ocak 2010 Dergi makalesi Açık Erişim

Ertekin, Kadriye; Oter, Ozlem; Ture, Mustafa; Denizalti, Serpil; Cetinkaya, Engin

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        "affiliation": "Dokuz Eylul Univ, Fac Arts & Sci, Dept Chem, TR-35160 Izmir, Turkey", 
        "name": "Ertekin, Kadriye"
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      {
        "affiliation": "Dokuz Eylul Univ, Fac Arts & Sci, Dept Chem, TR-35160 Izmir, Turkey", 
        "name": "Oter, Ozlem"
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      {
        "affiliation": "Dokuz Eylul Univ, Fac Arts & Sci, Dept Chem, TR-35160 Izmir, Turkey", 
        "name": "Ture, Mustafa"
      }, 
      {
        "affiliation": "Univ Ege, Dept Chem, Fac Sci, TR-35100 Izmir, Turkey", 
        "name": "Denizalti, Serpil"
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      {
        "affiliation": "Univ Ege, Dept Chem, Fac Sci, TR-35100 Izmir, Turkey", 
        "name": "Cetinkaya, Engin"
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    "description": "In this study, a very sensitive and highly selective irreversible optical chemical sensor (optode) for mercury ions was described. The sensing scheme was based on the interaction of Hg (II) with a newly synthesized fluoroionophore; chloro phenyl imino propenyl aniline (CPIPA) in plasticized PVC membrane. The sensor membranes were tested for the determination of mercury ion in aqueous solutions by batch and flow-through methods. The optodes allow determination of Hg (II) in the working range of 1.0 x 10(-9)-1.0 x 10(-5) M with a detection limit of 4.3 ppb. The sensor exhibited excellent selectivity for Hg (II) with respect to several common alkali, alkaline earth and transition metal ions. The association constant of the 1:1 complex formation for Hg (II) was found to be K(a) = 1.86 x 10(5) M(-1). The CPIPA exhibited high fluorescence quantum yield, long excitation and emission wavelength and high Stokes' shift values in the solid matrix which makes it compatible with solid state optics.", 
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    "journal": {
      "issue": "2", 
      "pages": "533-540", 
      "title": "JOURNAL OF FLUORESCENCE", 
      "volume": "20"
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    "publication_date": "2010-01-01", 
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    "title": "A Long Wavelength Excitable Fluorophore; Chloro Phenyl Imino Propenyl Aniline (CPIPA) for Selective Sensing of Hg (II)"
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