1 Ocak 2010 Dergi makalesi Açık Erişim

Ciftci, Goenuel Yenilmez; Dal, Hakan; Ecik, Esra Tanriverdi; Hokelek, Tuncer; Kilic, Adem; Senkuytu, Elif

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{
  "@context": "https://schema.org/", 
  "@id": 28301, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
      "name": "Ciftci, Goenuel Yenilmez"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Anadolu Univ, Dept Chem, TR-26470 Eskisehir, Turkey", 
      "name": "Dal, Hakan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
      "name": "Ecik, Esra Tanriverdi"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey", 
      "name": "Hokelek, Tuncer"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
      "name": "Kilic, Adem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
      "name": "Senkuytu, Elif"
    }
  ], 
  "datePublished": "2010-01-01", 
  "description": "In this study, the crystal structures of the dispiroansa spermine derivatives of cyclotriphosphazene are characterised for the first time. The reaction of spiro-, gem-disubstituted cyclotriphosphazene derivatives, N3P3Cl4R2 [R = NHPh, (HN(CH2)(3)NH)(0.5), (OCH2C(CH3)(2)CH2O)(0.5)], (1-3), with spermine (4), in aprotic solvents such as CH2Cl2 results in a series of dispirobino spermine derivatives of cyclotriphosphazene (5a, 6a, 7), namely spermine bridged compounds. Whereas, in protic solvents such as CHCl3 give, dispiroansa derivatives (8-10) namely tetracyclic cyclotriphosphazene. The new series of dispirobino and dispiroansa spermine derivatives of cyclotriphosphazene (5a, 6a, 7-10) have been characterised by elemental analysis, mass spectrometry, X-ray (for 5a, 8,10) and H-1, P-31 NMR spectroscopies. (C) 2009 Elsevier Ltd. All rights reserved.", 
  "headline": "The new dispirobino and dispiroansa spermine derivatives of cyclotriphosphazenes", 
  "identifier": 28301, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The new dispirobino and dispiroansa spermine derivatives of cyclotriphosphazenes", 
  "url": "https://aperta.ulakbim.gov.tr/record/28301"
}