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The new dispirobino and dispiroansa spermine derivatives of cyclotriphosphazenes

Ciftci, Goenuel Yenilmez; Dal, Hakan; Ecik, Esra Tanriverdi; Hokelek, Tuncer; Kilic, Adem; Senkuytu, Elif


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/28301</identifier>
  <creators>
    <creator>
      <creatorName>Ciftci, Goenuel Yenilmez</creatorName>
      <givenName>Goenuel Yenilmez</givenName>
      <familyName>Ciftci</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dal, Hakan</creatorName>
      <givenName>Hakan</givenName>
      <familyName>Dal</familyName>
      <affiliation>Anadolu Univ, Dept Chem, TR-26470 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ecik, Esra Tanriverdi</creatorName>
      <givenName>Esra Tanriverdi</givenName>
      <familyName>Ecik</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Hokelek, Tuncer</creatorName>
      <givenName>Tuncer</givenName>
      <familyName>Hokelek</familyName>
      <affiliation>Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kilic, Adem</creatorName>
      <givenName>Adem</givenName>
      <familyName>Kilic</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Senkuytu, Elif</creatorName>
      <givenName>Elif</givenName>
      <familyName>Senkuytu</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The New Dispirobino And Dispiroansa Spermine Derivatives Of Cyclotriphosphazenes</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/28301</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.poly.2009.12.022</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, the crystal structures of the dispiroansa spermine derivatives of cyclotriphosphazene are characterised for the first time. The reaction of spiro-, gem-disubstituted cyclotriphosphazene derivatives, N3P3Cl4R2 [R = NHPh, (HN(CH2)(3)NH)(0.5), (OCH2C(CH3)(2)CH2O)(0.5)], (1-3), with spermine (4), in aprotic solvents such as CH2Cl2 results in a series of dispirobino spermine derivatives of cyclotriphosphazene (5a, 6a, 7), namely spermine bridged compounds. Whereas, in protic solvents such as CHCl3 give, dispiroansa derivatives (8-10) namely tetracyclic cyclotriphosphazene. The new series of dispirobino and dispiroansa spermine derivatives of cyclotriphosphazene (5a, 6a, 7-10) have been characterised by elemental analysis, mass spectrometry, X-ray (for 5a, 8,10) and H-1, P-31 NMR spectroscopies. (C) 2009 Elsevier Ltd. All rights reserved.</description>
  </descriptions>
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