Dergi makalesi Açık Erişim
Sahin, Onur; Wallis, John D.
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/270536</identifier> <creators> <creator> <creatorName>Sahin, Onur</creatorName> <givenName>Onur</givenName> <familyName>Sahin</familyName> </creator> <creator> <creatorName>Wallis, John D.</creatorName> <givenName>John D.</givenName> <familyName>Wallis</familyName> <affiliation>Nottingham Trent Univ, Sch Sci & Technol, Clifton Lane, Nottingham NG1 8NS, England</affiliation> </creator> </creators> <titles> <title>Crystal Structure Of Bis(Mesityl)(Pyrrol-1-Yl)Borane</title> </titles> <publisher>Aperta</publisher> <publicationYear>2023</publicationYear> <dates> <date dateType="Issued">2023-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/270536</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1107/S2056989022011768</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract"><p>In the crystal structure of the title compound, C22H26BN, the B atom acts to reduce the delocalization of the nitrogen lone-pair electron density into the pyrrole ring, so that the two N-C bonds increase in length to 1.4005 (14) and 1.3981 (14) A degrees. The N-B bond length is 1.4425 (15) A degrees, which is longer than a typical N-B bond because the nitrogen lone pair is not fully available to participate in the bond.</p></description> </descriptions> </resource>
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