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Crystal structure of bis(mesityl)(pyrrol-1-yl)borane

Sahin, Onur; Wallis, John D.


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{
  "DOI": "10.1107/S2056989022011768", 
  "abstract": "<p>In the crystal structure of the title compound, C22H26BN, the B atom acts to reduce the delocalization of the nitrogen lone-pair electron density into the pyrrole ring, so that the two N-C bonds increase in length to 1.4005 (14) and 1.3981 (14) A degrees. The N-B bond length is 1.4425 (15) A degrees, which is longer than a typical N-B bond because the nitrogen lone pair is not fully available to participate in the bond.</p>", 
  "author": [
    {
      "family": "Sahin", 
      "given": " Onur"
    }, 
    {
      "family": "Wallis", 
      "given": " John D."
    }
  ], 
  "container_title": "ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS", 
  "id": "270536", 
  "issued": {
    "date-parts": [
      [
        2023, 
        1, 
        1
      ]
    ]
  }, 
  "page": "10", 
  "title": "Crystal structure of bis(mesityl)(pyrrol-1-yl)borane", 
  "type": "article-journal", 
  "volume": "79"
}
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