1 Ocak 2023 Dergi makalesi Açık Erişim

Buyukcakir, Onur; Yuksel, Recep; Begar, Ferit; Erdogmus, Mustafa; Arsakay, Madi; Lee, Sun Hwa; Kim, Sang Ouk; Ruoff, Rodney S. S.

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/267730</identifier>
  <creators>
    <creator>
      <creatorName>Buyukcakir, Onur</creatorName>
      <givenName>Onur</givenName>
      <familyName>Buyukcakir</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation>
    </creator>
    <creator>
      <creatorName>Yuksel, Recep</creatorName>
      <givenName>Recep</givenName>
      <familyName>Yuksel</familyName>
      <affiliation>Eskisehir Osmangazi Univ, Dept Chem, TR-26040 Eskisehir, Turkiye</affiliation>
    </creator>
    <creator>
      <creatorName>Begar, Ferit</creatorName>
      <givenName>Ferit</givenName>
      <familyName>Begar</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation>
    </creator>
    <creator>
      <creatorName>Erdogmus, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Erdogmus</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation>
    </creator>
    <creator>
      <creatorName>Arsakay, Madi</creatorName>
      <givenName>Madi</givenName>
      <familyName>Arsakay</familyName>
    </creator>
    <creator>
      <creatorName>Lee, Sun Hwa</creatorName>
      <givenName>Sun Hwa</givenName>
      <familyName>Lee</familyName>
      <affiliation>Inst Basic Sci IBS, Ctr Multidimens Carbon Mat, Ulsan 44919, South Korea</affiliation>
    </creator>
    <creator>
      <creatorName>Kim, Sang Ouk</creatorName>
      <givenName>Sang Ouk</givenName>
      <familyName>Kim</familyName>
    </creator>
    <creator>
      <creatorName>Ruoff, Rodney S. S.</creatorName>
      <givenName>Rodney S. S.</givenName>
      <familyName>Ruoff</familyName>
    </creator>
  </creators>
  <titles>
    <title>Ultralong-Life Quinone-Based Porous Organic Polymer Cathode For High-Performance Aqueous Zinc-Ion Batteries</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2023</publicationYear>
  <dates>
    <date dateType="Issued">2023-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/267730</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/acsaem.3c01163</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;We synthesized and studied a redox-active quinone-basedporousorganic polymer (rPOP) and found ultralong cycle life: it is a promisingorganic cathode for aqueous zinc-ion batteries (ZIBs). It has highphysicochemical stability and enhanced intrinsic conductivity fromits fused-aromatic conjugated skeleton. rPOP's high porosityallows for efficient Zn2+ infiltration through the poresduring charging-discharging cycles and contributes to the efficientutilization of redox-active quinone units. It delivers a specificcapacity of 120 mAh g(-1) at a current density of0.1 A g(-1) with a flat and long discharge plateau,which is critically important to provide a stable voltage output.It provides ultralong cycle life at a current density of 1.0 A g(-1) for 1000 and at 2.0 A g(-1) for 30 000cycles, with initial capacity retention of 95 and 66%, respectively.The co-insertion (Zn2+ and H+) charge storagemechanism was investigated using various electrochemical measurementsand ex/in situ structural characterization techniques, and is explainedherein. These findings contribute to a better understanding of thestructure-property relationship for rPOP and open a new avenuefor new organic cathode materials for high-performance next-generationaqueous batteries.&lt;/p&gt;</description>
  </descriptions>
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