Dergi makalesi Açık Erişim
Buyukcakir, Onur; Yuksel, Recep; Begar, Ferit; Erdogmus, Mustafa; Arsakay, Madi; Lee, Sun Hwa; Kim, Sang Ouk; Ruoff, Rodney S. S.
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/267730</identifier> <creators> <creator> <creatorName>Buyukcakir, Onur</creatorName> <givenName>Onur</givenName> <familyName>Buyukcakir</familyName> <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation> </creator> <creator> <creatorName>Yuksel, Recep</creatorName> <givenName>Recep</givenName> <familyName>Yuksel</familyName> <affiliation>Eskisehir Osmangazi Univ, Dept Chem, TR-26040 Eskisehir, Turkiye</affiliation> </creator> <creator> <creatorName>Begar, Ferit</creatorName> <givenName>Ferit</givenName> <familyName>Begar</familyName> <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation> </creator> <creator> <creatorName>Erdogmus, Mustafa</creatorName> <givenName>Mustafa</givenName> <familyName>Erdogmus</familyName> <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkiye</affiliation> </creator> <creator> <creatorName>Arsakay, Madi</creatorName> <givenName>Madi</givenName> <familyName>Arsakay</familyName> </creator> <creator> <creatorName>Lee, Sun Hwa</creatorName> <givenName>Sun Hwa</givenName> <familyName>Lee</familyName> <affiliation>Inst Basic Sci IBS, Ctr Multidimens Carbon Mat, Ulsan 44919, South Korea</affiliation> </creator> <creator> <creatorName>Kim, Sang Ouk</creatorName> <givenName>Sang Ouk</givenName> <familyName>Kim</familyName> </creator> <creator> <creatorName>Ruoff, Rodney S. S.</creatorName> <givenName>Rodney S. S.</givenName> <familyName>Ruoff</familyName> </creator> </creators> <titles> <title>Ultralong-Life Quinone-Based Porous Organic Polymer Cathode For High-Performance Aqueous Zinc-Ion Batteries</title> </titles> <publisher>Aperta</publisher> <publicationYear>2023</publicationYear> <dates> <date dateType="Issued">2023-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/267730</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/acsaem.3c01163</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract"><p>We synthesized and studied a redox-active quinone-basedporousorganic polymer (rPOP) and found ultralong cycle life: it is a promisingorganic cathode for aqueous zinc-ion batteries (ZIBs). It has highphysicochemical stability and enhanced intrinsic conductivity fromits fused-aromatic conjugated skeleton. rPOP's high porosityallows for efficient Zn2+ infiltration through the poresduring charging-discharging cycles and contributes to the efficientutilization of redox-active quinone units. It delivers a specificcapacity of 120 mAh g(-1) at a current density of0.1 A g(-1) with a flat and long discharge plateau,which is critically important to provide a stable voltage output.It provides ultralong cycle life at a current density of 1.0 A g(-1) for 1000 and at 2.0 A g(-1) for 30 000cycles, with initial capacity retention of 95 and 66%, respectively.The co-insertion (Zn2+ and H+) charge storagemechanism was investigated using various electrochemical measurementsand ex/in situ structural characterization techniques, and is explainedherein. These findings contribute to a better understanding of thestructure-property relationship for rPOP and open a new avenuefor new organic cathode materials for high-performance next-generationaqueous batteries.</p></description> </descriptions> </resource>
Görüntülenme | 0 |
İndirme | 0 |
Veri hacmi | 0 Bytes |
Tekil görüntülenme | 0 |
Tekil indirme | 0 |