1 Ocak 2022 Dergi makalesi Açık Erişim

Acar, Eminegul Genc; Ince, Tuncay; Yuzer, A. Celil; Yanalak, Gizem; Gecgel, Cihan; Aslan, Emre; Ince, Mine; Patir, Imren Hatay

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/262101</identifier>
  <creators>
    <creator>
      <creatorName>Acar, Eminegul Genc</creatorName>
      <givenName>Eminegul Genc</givenName>
      <familyName>Acar</familyName>
      <affiliation>Selcuk Univ, Dept Nanotechnol &amp; Adv Mat, TR-42250 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ince, Tuncay</creatorName>
      <givenName>Tuncay</givenName>
      <familyName>Ince</familyName>
      <affiliation>Mersin Univ, Adv Technol Res &amp; Applicat Ctr, TR-33343 Mersin, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yuzer, A. Celil</creatorName>
      <givenName>A. Celil</givenName>
      <familyName>Yuzer</familyName>
      <affiliation>Tarsus Univ, Vocat Sch Tech Sci Mersin Tarsus Organized Ind Zo, Dept Elect &amp; Automat, TR-33100 Mersin, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yanalak, Gizem</creatorName>
      <givenName>Gizem</givenName>
      <familyName>Yanalak</familyName>
      <affiliation>Selcuk Univ, Dept Biochem, TR-42250 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gecgel, Cihan</creatorName>
      <givenName>Cihan</givenName>
      <familyName>Gecgel</familyName>
      <affiliation>Mersin Univ, Adv Technol Res &amp; Applicat Ctr, TR-33343 Mersin, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Aslan, Emre</creatorName>
      <givenName>Emre</givenName>
      <familyName>Aslan</familyName>
      <affiliation>Selcuk Univ, Dept Biochem, TR-42250 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ince, Mine</creatorName>
      <givenName>Mine</givenName>
      <familyName>Ince</familyName>
      <affiliation>Tarsus Univ, Dept Nat &amp; Math Sci, TR-33400 Mersin, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Patir, Imren Hatay</creatorName>
      <givenName>Imren Hatay</givenName>
      <familyName>Patir</familyName>
      <affiliation>Selcuk Univ, Dept Biotechnol, TR-42250 Konya, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Solar-Light-Driven Photocatalytic Hydrogen Evolution By Push-Pull Thiophenoxy-Substituted Zinc Phthalocyanines</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2022</publicationYear>
  <dates>
    <date dateType="Issued">2022-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/262101</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1142/S1088424622500882</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Two zinc phthalocyanine derivatives (ZnPc 1 and 2) carrying bulky 2,6-diisopropylthiophenoxy peripheral substituents have been synthesized and their performances as photosensitizers in photochemical hydrogen production evaluated. To examine the influence of the spacer on the performance of ZnPc 1 and 2, the carboxyl group has been linked to the macrocycle ring either directly or via the phenyl ring, respectively. The photocatalytic activities of ZnPcs (ZnPc 1 and ZnPc 2) as sensitizers of TiO(2 )for hydrogen production were investigated in the presence of Pt. ZnPc 1 and ZnPc 2 sensitized TiO(2 )produced 0.687 mmolg(-1)h(-1) and 0.436 mmol g(-1)h(-1) hydrogens, which also reached 3.986 and 2.091 mmolg(-1) after 8h illumination, respectively, under visible light (&amp;gt;= 420 nm) irradiation. In addition, STH efficiencies of ZnPc 1/TiO2 and ZnPc 2/TiO2 were determined as 1.77% and 1.12%, respectively. ZnPc 1/TiO2 exhibited 1.9-fold more photocatalytic hydrogen amount than ZnPc 2/TiO2, and the hydrogen evolution performance of the photocatalyst in the presence of Pt enhanced to 3.021 mmol g(-1)h(-1) and 0.911mmol g(-1)h(-1) for ZnPc 1 and ZnPc 2, respectively.</description>
  </descriptions>
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