1 Ocak 2022 Dergi makalesi Açık Erişim

Acar, Eminegul Genc; Ince, Tuncay; Yuzer, A. Celil; Yanalak, Gizem; Gecgel, Cihan; Aslan, Emre; Ince, Mine; Patir, Imren Hatay

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{
  "DOI": "10.1142/S1088424622500882", 
  "abstract": "Two zinc phthalocyanine derivatives (ZnPc 1 and 2) carrying bulky 2,6-diisopropylthiophenoxy peripheral substituents have been synthesized and their performances as photosensitizers in photochemical hydrogen production evaluated. To examine the influence of the spacer on the performance of ZnPc 1 and 2, the carboxyl group has been linked to the macrocycle ring either directly or via the phenyl ring, respectively. The photocatalytic activities of ZnPcs (ZnPc 1 and ZnPc 2) as sensitizers of TiO(2 )for hydrogen production were investigated in the presence of Pt. ZnPc 1 and ZnPc 2 sensitized TiO(2 )produced 0.687 mmolg(-1)h(-1) and 0.436 mmol g(-1)h(-1) hydrogens, which also reached 3.986 and 2.091 mmolg(-1) after 8h illumination, respectively, under visible light (>= 420 nm) irradiation. In addition, STH efficiencies of ZnPc 1/TiO2 and ZnPc 2/TiO2 were determined as 1.77% and 1.12%, respectively. ZnPc 1/TiO2 exhibited 1.9-fold more photocatalytic hydrogen amount than ZnPc 2/TiO2, and the hydrogen evolution performance of the photocatalyst in the presence of Pt enhanced to 3.021 mmol g(-1)h(-1) and 0.911mmol g(-1)h(-1) for ZnPc 1 and ZnPc 2, respectively.", 
  "author": [
    {
      "family": "Acar", 
      "given": " Eminegul Genc"
    }, 
    {
      "family": "Ince", 
      "given": " Tuncay"
    }, 
    {
      "family": "Yuzer", 
      "given": " A. Celil"
    }, 
    {
      "family": "Yanalak", 
      "given": " Gizem"
    }, 
    {
      "family": "Gecgel", 
      "given": " Cihan"
    }, 
    {
      "family": "Aslan", 
      "given": " Emre"
    }, 
    {
      "family": "Ince", 
      "given": " Mine"
    }, 
    {
      "family": "Patir", 
      "given": " Imren Hatay"
    }
  ], 
  "container_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES", 
  "id": "262101", 
  "issued": {
    "date-parts": [
      [
        2022, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Solar-light-driven photocatalytic hydrogen evolution by push-pull thiophenoxy-substituted zinc phthalocyanines", 
  "type": "article-journal"
}