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Single crystal X-ray structure and optical properties of anthraquinone-based dyes

Kurtoglu, Nurcan; Aslantas, Mehmet; Zengin, Huseyin; Sahin, Ertan; Kurtoglu, Mukerrem


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Kurtoglu, Nurcan</dc:creator>
  <dc:creator>Aslantas, Mehmet</dc:creator>
  <dc:creator>Zengin, Huseyin</dc:creator>
  <dc:creator>Sahin, Ertan</dc:creator>
  <dc:creator>Kurtoglu, Mukerrem</dc:creator>
  <dc:date>2010-01-01</dc:date>
  <dc:description>This study focuses on the preparation, single crystal X-ray diffraction, characterization, and optical properties of some anthraquinone-based dyes. The anthraquinone-based antimicrobial dye N-{2-[(9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]-2-oxoethyl}-N,N-dimethylbutan-1-aminium chloride monohydrate (III) was obtained from 1-aminoanthraquinone (I) via 2-chloro-N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)acetamide (II) using known preparation and characterization methods. Single crystal X-ray diffraction analysis of III revealed a monoclinic system, space group P2(1)/n, Z = 4. Photoluminescence properties of anthraquinone dyes I-III were also investigated. These dyes gave an intense emission (lambda(max) = 341 nm) upon the irradiation by UV light and showed photoluminescence quantum yields of 73 %, 66 %, and 61 % with long excited-state lifetimes of 6.87 ns, 6.14 ns, and 5.69 ns, respectively. These anthraquinone dyes are of interest as an organic light emitting material for electroluminescent devices.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/26199</dc:identifier>
  <dc:identifier>oai:zenodo.org:26199</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>CHEMICAL PAPERS 64(5) 645-651</dc:source>
  <dc:title>Single crystal X-ray structure and optical properties of anthraquinone-based dyes</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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