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Single crystal X-ray structure and optical properties of anthraquinone-based dyes

Kurtoglu, Nurcan; Aslantas, Mehmet; Zengin, Huseyin; Sahin, Ertan; Kurtoglu, Mukerrem


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/26199</identifier>
  <creators>
    <creator>
      <creatorName>Kurtoglu, Nurcan</creatorName>
      <givenName>Nurcan</givenName>
      <familyName>Kurtoglu</familyName>
      <affiliation>Sutcu Imam Univ, Fac Engn &amp; Architecture, Dept Text Engn, TR-46050 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Aslantas, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Aslantas</familyName>
      <affiliation>Sutcu Imam Univ, Dept Phys, Fac Sci &amp; Arts, TR-46050 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Zengin, Huseyin</creatorName>
      <givenName>Huseyin</givenName>
      <familyName>Zengin</familyName>
      <affiliation>Sutcu Imam Univ, Dept Chem, Fac Sci &amp; Arts, TR-46050 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sahin, Ertan</creatorName>
      <givenName>Ertan</givenName>
      <familyName>Sahin</familyName>
      <affiliation>Ataturk Univ, Fac Sci &amp; Arts, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kurtoglu, Mukerrem</creatorName>
      <givenName>Mukerrem</givenName>
      <familyName>Kurtoglu</familyName>
      <affiliation>Sutcu Imam Univ, Dept Chem, Fac Sci &amp; Arts, TR-46050 Kahramanmaras, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Single Crystal X-Ray Structure And Optical Properties Of Anthraquinone-Based Dyes</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/26199</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.2478/s11696-010-0037-3</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">This study focuses on the preparation, single crystal X-ray diffraction, characterization, and optical properties of some anthraquinone-based dyes. The anthraquinone-based antimicrobial dye N-{2-[(9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]-2-oxoethyl}-N,N-dimethylbutan-1-aminium chloride monohydrate (III) was obtained from 1-aminoanthraquinone (I) via 2-chloro-N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)acetamide (II) using known preparation and characterization methods. Single crystal X-ray diffraction analysis of III revealed a monoclinic system, space group P2(1)/n, Z = 4. Photoluminescence properties of anthraquinone dyes I-III were also investigated. These dyes gave an intense emission (lambda(max) = 341 nm) upon the irradiation by UV light and showed photoluminescence quantum yields of 73 %, 66 %, and 61 % with long excited-state lifetimes of 6.87 ns, 6.14 ns, and 5.69 ns, respectively. These anthraquinone dyes are of interest as an organic light emitting material for electroluminescent devices.</description>
  </descriptions>
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