1 Ocak 2022 Dergi makalesi Açık Erişim

Catiker, Efkan; Hamzacebi, Aycanur

Dublin Core

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  <dc:creator>Catiker, Efkan</dc:creator>
  <dc:creator>Hamzacebi, Aycanur</dc:creator>
  <dc:date>2022-01-01</dc:date>
  <dc:description>A series of poly(beta-alanine-b-lactone)s were prepared by combination of hydrogen-transfer polymerization (HTP) of acrylamide and anionic ring-opening polymerization (AROP) of beta-propiolactone, alpha-methyl propiolactone, beta-butyrolactone, and delta-valerolactone. Poly-beta-alanine (PBA) having a living anionic end-group for a further extension was obtained via HTP of acrylamide. Then, the anionic end-group on PBA chains was used as initiation sites for AROP of the lactones. By varying acrylamide feeds, a series of copolymers was obtained with a hard segment (beta-alanine) content between 6.86 and 36.82 mol%. Elemental analyses and spectral data (MALDI-MS, H-1-NMR, and FT-IR) for all new products were consistent with the proposed structures.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/261419</dc:identifier>
  <dc:identifier>oai:aperta.ulakbim.gov.tr:261419</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>MACROMOLECULAR RESEARCH 30(5) 305-313</dc:source>
  <dc:title>A Novel Strategy for Poly(beta-alanine-b-lactone)s: Sequentially HTP and AROP</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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