1 Ocak 2022 Dergi makalesi Açık Erişim

Catiker, Efkan; Hamzacebi, Aycanur

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{
  "@context": "https://schema.org/", 
  "@id": 261419, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey", 
      "name": "Catiker, Efkan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey", 
      "name": "Hamzacebi, Aycanur"
    }
  ], 
  "datePublished": "2022-01-01", 
  "description": "A series of poly(beta-alanine-b-lactone)s were prepared by combination of hydrogen-transfer polymerization (HTP) of acrylamide and anionic ring-opening polymerization (AROP) of beta-propiolactone, alpha-methyl propiolactone, beta-butyrolactone, and delta-valerolactone. Poly-beta-alanine (PBA) having a living anionic end-group for a further extension was obtained via HTP of acrylamide. Then, the anionic end-group on PBA chains was used as initiation sites for AROP of the lactones. By varying acrylamide feeds, a series of copolymers was obtained with a hard segment (beta-alanine) content between 6.86 and 36.82 mol%. Elemental analyses and spectral data (MALDI-MS, H-1-NMR, and FT-IR) for all new products were consistent with the proposed structures.", 
  "headline": "A Novel Strategy for Poly(beta-alanine-b-lactone)s: Sequentially HTP and AROP", 
  "identifier": 261419, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "A Novel Strategy for Poly(beta-alanine-b-lactone)s: Sequentially HTP and AROP", 
  "url": "https://aperta.ulakbim.gov.tr/record/261419"
}