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An AB(2)-Type Hyperbranched Supramolecular Polymer Based on Calix[4]Pyrrole Anion Recognition: Construction, Stimuli-Responsiveness, and Morphology Tuning

Unlu, Fatma Yelda; Aydogan, Abdullah


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        "name": "Unlu, Fatma Yelda"
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        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Maslak, Turkey", 
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    "description": "An AB(2)-type monomer comprised of a calix[4]pyrrole skeleton and alternating bis-carboxylate units is reported and used for the construction of a novel supramolecular hyperbranched polymer based on anion recognition ability of calix[4]pyrrole. H-1-, DOSY-NMR spectroscopy, viscosity measurements, and dynamic light scattering techniques are used for the characterization of the supramolecular hyperbranched polymer exhibiting thermo-, pH-, and chemical responsiveness, as well as concentration dependent morphology tune as inferred from electron microscopy analyses. The present study enriches the field of supramolecular polymers with a new construction motif, building block, and provides a simple approach for the fabrication of smart polymer material with multi-responsiveness and -morphologies.", 
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