1 Ocak 2022 Dergi makalesi Açık Erişim

Unlu, Fatma Yelda; Aydogan, Abdullah

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/261191</identifier>
  <creators>
    <creator>
      <creatorName>Unlu, Fatma Yelda</creatorName>
      <givenName>Fatma Yelda</givenName>
      <familyName>Unlu</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Maslak, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Aydogan, Abdullah</creatorName>
      <givenName>Abdullah</givenName>
      <familyName>Aydogan</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Maslak, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>An Ab(2)-Type Hyperbranched Supramolecular Polymer Based On Calix[4]Pyrrole Anion Recognition: Construction, Stimuli-Responsiveness, And Morphology Tuning</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2022</publicationYear>
  <dates>
    <date dateType="Issued">2022-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/261191</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/marc.202200447</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">An AB(2)-type monomer comprised of a calix[4]pyrrole skeleton and alternating bis-carboxylate units is reported and used for the construction of a novel supramolecular hyperbranched polymer based on anion recognition ability of calix[4]pyrrole. H-1-, DOSY-NMR spectroscopy, viscosity measurements, and dynamic light scattering techniques are used for the characterization of the supramolecular hyperbranched polymer exhibiting thermo-, pH-, and chemical responsiveness, as well as concentration dependent morphology tune as inferred from electron microscopy analyses. The present study enriches the field of supramolecular polymers with a new construction motif, building block, and provides a simple approach for the fabrication of smart polymer material with multi-responsiveness and -morphologies.</description>
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