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Solution-processable donor-pi-acceptor type thieno[3,2-b]thiophene derivatives; synthesis, photophysical properties and applications

Isci, Recep; Wan, Li; Topal, Sebahat; Gunturkun, Dilara; Campbell, Alasdair James; Ozturk, Turan


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        "affiliation": "Istanbul Tech Univ, Chem Dept, TR-34469 Istanbul, Turkey", 
        "name": "Isci, Recep"
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      {
        "name": "Wan, Li"
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      {
        "affiliation": "Istanbul Tech Univ, Chem Dept, TR-34469 Istanbul, Turkey", 
        "name": "Topal, Sebahat"
      }, 
      {
        "affiliation": "Istanbul Tech Univ, Chem Dept, TR-34469 Istanbul, Turkey", 
        "name": "Gunturkun, Dilara"
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      {
        "name": "Campbell, Alasdair James"
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    "description": "Two novel donor-pi-acceptor (D-pi-A)-type pull-push materials, M1 and M2, having triphenylamine as a donor and dimesitylboron as an acceptor, linked through a thieno[3,2-b]thiophene (TT) pi-conjugated spacer bearing different functional substituents, such as -PhCN and -Ph, were synthesized and fabricated via a solution process for OLED applications. They exhibited mega Stokes shifts of 120 nm and emissions both in the solid-state and in solution. The monomers M1 and M2 had strong intramolecular charge-transfer behaviors; the solid-state quantum yields were recorded to be 76 and 72% and the solution quantum efficiencies were determined to be 100 and 95%, respectively. The solution-processed OLEDs were fabricated using low turn-on voltages, which had performances with maximum power, current and external quantum efficiencies of around 8 lm W-1, 14.1 cd A(-1) and 4.78%, respectively, displaying emission colors from blue to green and yellowish green. The materials had strong fluorescence emission colors between yellowish and bluish under UV irradiation.", 
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      "issue": "29", 
      "pages": "10719-10727", 
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