Dergi makalesi Açık Erişim

Polybenzimidazole-modified carbon nanotubes as a support material for platinum-based high-temperature proton exchange membrane fuel cell electrocatalysts

Eren, Enis Oguzhan; Ozkan, Necati; Devrim, Yilser


JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 239668, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Middle East Tech Univ, Polymer Sci & Technol, TR-06800 Ankara, Turkey", 
      "name": "Eren, Enis Oguzhan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle East Tech Univ, Polymer Sci & Technol, TR-06800 Ankara, Turkey", 
      "name": "Ozkan, Necati"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Atilim Univ, Energy Syst Engn, TR-06836 Ankara, Turkey", 
      "name": "Devrim, Yilser"
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "We fabricate polybenzimidazole (PBI) wrapped carbon nanotubes (MWCNTs) as support material for platinum-based fuel cell electrocatalyst. With the aid of microwave-assisted polyol reduction, we obtain very fine platinum (Pt) nanoparticles on PBI/MWCNT support while reducing the amount of Pt waste during synthesis. Cyclic voltammetry (CV) concludes that Pt-PBI/MWCNT has 43.0 m(2) g(-1) of electrochemically active surface area (ECSA) to catalyze hydrogen oxidation. Furthermore, after the 1000th cycle, Pt-PBI/MWCNT preserves almost 80% of its maximum ECSA, meaning that Pt-PBI/MWCNT is much more durable than the Pt/MWCNT and commercial Pt/C. High-temperature proton exchange membrane fuel cell (HT-PEMFC) performance tests are conducted under H-2/Air conditions at the temperatures ranging from 150 degrees C to 180 degrees C. Nevertheless, tests conclude that the maximum power density values of the Pt-PBI/MWCNT are found inferior to the Pt/C at all temperatures (e.g., 47 vs. 62 mW cm(-2) at 180 degrees C), suggesting that some balance between durability and performance has to be taken into consideration. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", 
  "headline": "Polybenzimidazole-modified carbon nanotubes as a support material for platinum-based high-temperature proton exchange membrane fuel cell electrocatalysts", 
  "identifier": 239668, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Polybenzimidazole-modified carbon nanotubes as a support material for platinum-based high-temperature proton exchange membrane fuel cell electrocatalysts", 
  "url": "https://aperta.ulakbim.gov.tr/record/239668"
}
22
9
görüntülenme
indirilme
Görüntülenme 22
İndirme 9
Veri hacmi 2.3 kB
Tekil görüntülenme 21
Tekil indirme 9

Alıntı yap