1 Ocak 2021 Dergi makalesi Açık Erişim

Kanova, Nilay; Dundar, Buse Aysen; Kelgokmen, Yilmaz; Zora, Metin

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        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Kanova, Nilay"
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      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Dundar, Buse Aysen"
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      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Kelgokmen, Yilmaz"
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      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Zora, Metin"
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    "description": "A one pot two step protocol for the synthesis of 2-acetyl-1H-pyrroles from N-propargylic beta-enaminones was described. When treated with zinc chloride in refluxing chloroform, N-propargylic beta-enaminones produced in situ 2-methylene-2,3-dihydro-1,4-oxazepines, which, upon further refluxing in methanol with zinc chloride, afforded 2-acetyl-1H-pyrroles. The process was found to be general for a wide variety of N-propargylic beta-enaminones and yielded a diverse range of 2-acetyl-1H-pyrroles in good to high yields with large substrate scope and good functional group tolerance. This operationally easy method may provide a rapid access to functionalized 2-acetyl-1H-pyrroles of pharmacological interest.", 
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    "journal": {
      "issue": "9", 
      "pages": "6289-6304", 
      "title": "JOURNAL OF ORGANIC CHEMISTRY", 
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    "title": "One-Pot Synthesis of 2-Acety1-1H-pyrroles from N-Propargylic beta-Enaminones via Intermediacy of 1,4-Oxazepines"
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