1 Ocak 2021 Dergi makalesi Açık Erişim

Kanova, Nilay; Dundar, Buse Aysen; Kelgokmen, Yilmaz; Zora, Metin

JSON

{
  "conceptrecid": "231355", 
  "created": "2022-10-07T08:06:28.901001+00:00", 
  "doi": "10.1021/acs.joc.1c00077", 
  "files": [
    {
      "bucket": "f2f637c3-d426-4bb9-b36f-02febeb4d71d", 
      "checksum": "md5:9963796fc6d4210cd9c4c50ec91f34c3", 
      "key": "bib-05c71f74-6980-43b3-b63b-68ec65dbf732.txt", 
      "links": {
        "self": "https://aperta.ulakbim.gov.tr/api/files/f2f637c3-d426-4bb9-b36f-02febeb4d71d/bib-05c71f74-6980-43b3-b63b-68ec65dbf732.txt"
      }, 
      "size": 217, 
      "type": "txt"
    }
  ], 
  "id": 231356, 
  "links": {
    "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1021/acs.joc.1c00077.svg", 
    "bucket": "https://aperta.ulakbim.gov.tr/api/files/f2f637c3-d426-4bb9-b36f-02febeb4d71d", 
    "doi": "https://doi.org/10.1021/acs.joc.1c00077", 
    "html": "https://aperta.ulakbim.gov.tr/record/231356", 
    "latest": "https://aperta.ulakbim.gov.tr/api/records/231356", 
    "latest_html": "https://aperta.ulakbim.gov.tr/record/231356"
  }, 
  "metadata": {
    "access_right": "open", 
    "access_right_category": "success", 
    "communities": [
      {
        "id": "tubitak-destekli-proje-yayinlari"
      }
    ], 
    "creators": [
      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Kanova, Nilay"
      }, 
      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Dundar, Buse Aysen"
      }, 
      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Kelgokmen, Yilmaz"
      }, 
      {
        "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Zora, Metin"
      }
    ], 
    "description": "A one pot two step protocol for the synthesis of 2-acetyl-1H-pyrroles from N-propargylic beta-enaminones was described. When treated with zinc chloride in refluxing chloroform, N-propargylic beta-enaminones produced in situ 2-methylene-2,3-dihydro-1,4-oxazepines, which, upon further refluxing in methanol with zinc chloride, afforded 2-acetyl-1H-pyrroles. The process was found to be general for a wide variety of N-propargylic beta-enaminones and yielded a diverse range of 2-acetyl-1H-pyrroles in good to high yields with large substrate scope and good functional group tolerance. This operationally easy method may provide a rapid access to functionalized 2-acetyl-1H-pyrroles of pharmacological interest.", 
    "doi": "10.1021/acs.joc.1c00077", 
    "has_grant": false, 
    "journal": {
      "issue": "9", 
      "pages": "6289-6304", 
      "title": "JOURNAL OF ORGANIC CHEMISTRY", 
      "volume": "86"
    }, 
    "license": {
      "id": "cc-by"
    }, 
    "publication_date": "2021-01-01", 
    "relations": {
      "version": [
        {
          "count": 1, 
          "index": 0, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "231356"
          }, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "231355"
          }
        }
      ]
    }, 
    "resource_type": {
      "subtype": "article", 
      "title": "Dergi makalesi", 
      "type": "publication"
    }, 
    "science_branches": [
      "Di\u011fer"
    ], 
    "title": "One-Pot Synthesis of 2-Acety1-1H-pyrroles from N-Propargylic beta-Enaminones via Intermediacy of 1,4-Oxazepines"
  }, 
  "owners": [
    1
  ], 
  "revision": 1, 
  "stats": {
    "downloads": 5.0, 
    "unique_downloads": 5.0, 
    "unique_views": 28.0, 
    "version_downloads": 5.0, 
    "version_unique_downloads": 5.0, 
    "version_unique_views": 28.0, 
    "version_views": 30.0, 
    "version_volume": 1085.0, 
    "views": 30.0, 
    "volume": 1085.0
  }, 
  "updated": "2022-10-07T08:06:28.949132+00:00"
}