1 Ocak 2021 Dergi makalesi Açık Erişim

Cetinkaya, Ahmet; Sadak, Ali Enis; Ayhan, Mehmet Menaf; Zorlu, Yunus; Kahveci, Muhammet U.

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        "affiliation": "Yildiz Tech Univ, Dept Bioengn, Fac Chem & Met Engn, Davutpasa Campus, TR-34210 Istanbul, Turkey", 
        "name": "Cetinkaya, Ahmet"
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      {
        "affiliation": "TUBITAK UME, Chem Grp Labs, TR-41470 Kocaeli, Turkey", 
        "name": "Sadak, Ali Enis"
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      {
        "affiliation": "Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey", 
        "name": "Ayhan, Mehmet Menaf"
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      {
        "affiliation": "Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey", 
        "name": "Zorlu, Yunus"
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      {
        "affiliation": "Istanbul Tech Univ, Fac Sci & Letters, Dept Chem, TR-34467 Istanbul, Turkey", 
        "name": "Kahveci, Muhammet U."
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    "description": "Inverse electron demand Diels-Alder (IEDDA) reaction has been employed as a powerful ligation in several fields. In the current work, a synthetic approach relying on IEDDA reaction is developed for preparation of a porphyrin based covalent organic polymer (PoTz-COP). A tetra-norbornene functional porphyrin is chosen as the core and a bis-tetrazine as the linker. The PoTz-COP is readily formed by just mixing the components without a catalyst and under mild conditions. Chemical structure, morphology (XRD, SEM-EDX), porosity (BET), thermal stability (TGA), optical and gas sorption (CO2 uptake) and selectivity (CO2/N-2) properties via Myers and Prausnitz's ideal adsorbed solution theory (IAST) are investigated. PoTz-COP shows remarkably high adsorption selectivity of CO2 over N-2 as found 80, 42, and 47 at 50/50 ratio; 84, 39 and 40 at 15/85 ratio; and 84, 39 and 38 at 05/95 ratio at temperatures of 273 K, 298 K and 320 K at 1.1 bar pressure respectively. The optical band gap is determined relatively narrow as 1.66 eV.", 
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      "title": "EUROPEAN POLYMER JOURNAL", 
      "volume": "157"
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    "title": "Porphyrin-based covalent organic polymer by inverse electron demand Diels-Alder reaction"
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