1 Ocak 2021 Dergi makalesi Açık Erişim

Cetinkaya, Ahmet; Sadak, Ali Enis; Ayhan, Mehmet Menaf; Zorlu, Yunus; Kahveci, Muhammet U.

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{
  "DOI": "10.1016/j.eurpolymj.2021.110664", 
  "abstract": "Inverse electron demand Diels-Alder (IEDDA) reaction has been employed as a powerful ligation in several fields. In the current work, a synthetic approach relying on IEDDA reaction is developed for preparation of a porphyrin based covalent organic polymer (PoTz-COP). A tetra-norbornene functional porphyrin is chosen as the core and a bis-tetrazine as the linker. The PoTz-COP is readily formed by just mixing the components without a catalyst and under mild conditions. Chemical structure, morphology (XRD, SEM-EDX), porosity (BET), thermal stability (TGA), optical and gas sorption (CO2 uptake) and selectivity (CO2/N-2) properties via Myers and Prausnitz's ideal adsorbed solution theory (IAST) are investigated. PoTz-COP shows remarkably high adsorption selectivity of CO2 over N-2 as found 80, 42, and 47 at 50/50 ratio; 84, 39 and 40 at 15/85 ratio; and 84, 39 and 38 at 05/95 ratio at temperatures of 273 K, 298 K and 320 K at 1.1 bar pressure respectively. The optical band gap is determined relatively narrow as 1.66 eV.", 
  "author": [
    {
      "family": "Cetinkaya", 
      "given": " Ahmet"
    }, 
    {
      "family": "Sadak", 
      "given": " Ali Enis"
    }, 
    {
      "family": "Ayhan", 
      "given": " Mehmet Menaf"
    }, 
    {
      "family": "Zorlu", 
      "given": " Yunus"
    }, 
    {
      "family": "Kahveci", 
      "given": " Muhammet U."
    }
  ], 
  "container_title": "EUROPEAN POLYMER JOURNAL", 
  "id": "229694", 
  "issued": {
    "date-parts": [
      [
        2021, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Porphyrin-based covalent organic polymer by inverse electron demand Diels-Alder reaction", 
  "type": "article-journal", 
  "volume": "157"
}