Dergi makalesi Açık Erişim
Ekiz, Okan Oner; Urel, Mustafa; Guner, Hasan; Mizrak, Alpay Koray; Dana, Aykutlu
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<identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/22755</identifier>
<creators>
<creator>
<creatorName>Ekiz, Okan Oner</creatorName>
<givenName>Okan Oner</givenName>
<familyName>Ekiz</familyName>
<affiliation>Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey</affiliation>
</creator>
<creator>
<creatorName>Urel, Mustafa</creatorName>
<givenName>Mustafa</givenName>
<familyName>Urel</familyName>
<affiliation>Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey</affiliation>
</creator>
<creator>
<creatorName>Guner, Hasan</creatorName>
<givenName>Hasan</givenName>
<familyName>Guner</familyName>
<affiliation>Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey</affiliation>
</creator>
<creator>
<creatorName>Mizrak, Alpay Koray</creatorName>
<givenName>Alpay Koray</givenName>
<familyName>Mizrak</familyName>
<affiliation>Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey</affiliation>
</creator>
<creator>
<creatorName>Dana, Aykutlu</creatorName>
<givenName>Aykutlu</givenName>
<familyName>Dana</familyName>
<affiliation>Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey</affiliation>
</creator>
</creators>
<titles>
<title>Reversible Electrical Reduction And Oxidation Of Graphene Oxide</title>
</titles>
<publisher>Aperta</publisher>
<publicationYear>2011</publicationYear>
<dates>
<date dateType="Issued">2011-01-01</date>
</dates>
<resourceType resourceTypeGeneral="Text">Journal article</resourceType>
<alternateIdentifiers>
<alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/22755</alternateIdentifier>
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<relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/nn1014215</relatedIdentifier>
</relatedIdentifiers>
<rightsList>
<rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
<rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
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<descriptions>
<description descriptionType="Abstract">We demonstrate that graphene oxide can be reversibly reduced and oxidized using electrical stimulus. Controlled reduction and oxidation in two-terminal devices containing multilayer graphene oxide films are shown to result in switching between partially reduced graphene oxide and graphene, a process which modifies the electronic and optical properties. High-resolution tunneling current and electrostatic force imaging reveal that graphene oxide islands are formed on multilayer graphene, turning graphene into a self-assembled heterostructure random nanomesh. Charge storage and resistive switching behavior is observed in two-terminal devices made of multilayer graphene oxide films, correlated with electrochromic effects. Tip-induced reduction and oxidation are also demonstrated. Results are discussed in terms of thermodynamics of oxidation and reduction reactions.</description>
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