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Ekiz, Okan Oner; Urel, Mustafa; Guner, Hasan; Mizrak, Alpay Koray; Dana, Aykutlu
{
"DOI": "10.1021/nn1014215",
"abstract": "We demonstrate that graphene oxide can be reversibly reduced and oxidized using electrical stimulus. Controlled reduction and oxidation in two-terminal devices containing multilayer graphene oxide films are shown to result in switching between partially reduced graphene oxide and graphene, a process which modifies the electronic and optical properties. High-resolution tunneling current and electrostatic force imaging reveal that graphene oxide islands are formed on multilayer graphene, turning graphene into a self-assembled heterostructure random nanomesh. Charge storage and resistive switching behavior is observed in two-terminal devices made of multilayer graphene oxide films, correlated with electrochromic effects. Tip-induced reduction and oxidation are also demonstrated. Results are discussed in terms of thermodynamics of oxidation and reduction reactions.",
"author": [
{
"family": "Ekiz",
"given": " Okan Oner"
},
{
"family": "Urel",
"given": " Mustafa"
},
{
"family": "Guner",
"given": " Hasan"
},
{
"family": "Mizrak",
"given": " Alpay Koray"
},
{
"family": "Dana",
"given": " Aykutlu"
}
],
"container_title": "ACS NANO",
"id": "22755",
"issue": "4",
"issued": {
"date-parts": [
[
2011,
1,
1
]
]
},
"page": "2475-2482",
"title": "Reversible Electrical Reduction and Oxidation of Graphene Oxide",
"type": "article-journal",
"volume": "5"
}
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