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Karimi-Maleh, Hassan; Cellat, Kemal; Arikan, Kubilay; Savk, Aysun; Karimi, Fatemeh; Sen, Fatih
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/11725</identifier> <creators> <creator> <creatorName>Karimi-Maleh, Hassan</creatorName> <givenName>Hassan</givenName> <familyName>Karimi-Maleh</familyName> </creator> <creator> <creatorName>Cellat, Kemal</creatorName> <givenName>Kemal</givenName> <familyName>Cellat</familyName> <affiliation>Dumlupinar Univ, Fac Arts & Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation> </creator> <creator> <creatorName>Arikan, Kubilay</creatorName> <givenName>Kubilay</givenName> <familyName>Arikan</familyName> <affiliation>Dumlupinar Univ, Fac Arts & Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation> </creator> <creator> <creatorName>Savk, Aysun</creatorName> <givenName>Aysun</givenName> <familyName>Savk</familyName> <affiliation>Dumlupinar Univ, Fac Arts & Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation> </creator> <creator> <creatorName>Karimi, Fatemeh</creatorName> <givenName>Fatemeh</givenName> <familyName>Karimi</familyName> </creator> <creator> <creatorName>Sen, Fatih</creatorName> <givenName>Fatih</givenName> <familyName>Sen</familyName> <affiliation>Dumlupinar Univ, Fac Arts & Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation> </creator> </creators> <titles> <title>Palladium-Nickel Nanoparticles Decorated On Functionalized-Mwcnt For High Precision Non-Enzymatic Glucose Sensing</title> </titles> <publisher>Aperta</publisher> <publicationYear>2020</publicationYear> <dates> <date dateType="Issued">2020-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/11725</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.matchemphys.2020.123042</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">In this study, we report the synthesis and application of palladium-nickel nanoparticles decorated on functionalized-multiwall carbon nanotube Pd-Ni@f-MWCNT and employed as a sensitive non-enzymatic electrochemical glucose sensor. The composition and crystal structure was characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and Raman spectroscopy. The surface morphology of Pd-Ni@f-MWCNT was investigated by a transmission electron microscopy (TEM). The electrochemical response of the Pd-Ni@f-MWCNT to glucose was examined via the cyclic voltammetry. Results revealed that the prepared electrode exhibits high electrocatalytic activity for the oxidation of glucose into gluconolactone. The ampero-metric response of the Pd-Ni@f-MWCNT electrode to glucose was investigated at a potential of 0.5 V that demonstrated an extended linear range of from 0.01 to 1.4 mM, very low detection limit of 0.026 mu M, very high sensitivity at 71 mu A mM(-1) cm(-2) , as well as good reproducibility, high stability and applicability for the real sample analysis. The reliability of the developed sensor was verified by comparison with a commercially available glucometer. The obtained results indicate that Pd-Ni@f-MWCNT is a promising candidate for electrochemical glucose sensing.</description> </descriptions> </resource>
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