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Palladium-Nickel nanoparticles decorated on Functionalized-MWCNT for high precision non-enzymatic glucose sensing

Karimi-Maleh, Hassan; Cellat, Kemal; Arikan, Kubilay; Savk, Aysun; Karimi, Fatemeh; Sen, Fatih


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/11725</identifier>
  <creators>
    <creator>
      <creatorName>Karimi-Maleh, Hassan</creatorName>
      <givenName>Hassan</givenName>
      <familyName>Karimi-Maleh</familyName>
    </creator>
    <creator>
      <creatorName>Cellat, Kemal</creatorName>
      <givenName>Kemal</givenName>
      <familyName>Cellat</familyName>
      <affiliation>Dumlupinar Univ, Fac Arts &amp; Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Arikan, Kubilay</creatorName>
      <givenName>Kubilay</givenName>
      <familyName>Arikan</familyName>
      <affiliation>Dumlupinar Univ, Fac Arts &amp; Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Savk, Aysun</creatorName>
      <givenName>Aysun</givenName>
      <familyName>Savk</familyName>
      <affiliation>Dumlupinar Univ, Fac Arts &amp; Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Karimi, Fatemeh</creatorName>
      <givenName>Fatemeh</givenName>
      <familyName>Karimi</familyName>
    </creator>
    <creator>
      <creatorName>Sen, Fatih</creatorName>
      <givenName>Fatih</givenName>
      <familyName>Sen</familyName>
      <affiliation>Dumlupinar Univ, Fac Arts &amp; Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Palladium-Nickel Nanoparticles Decorated On Functionalized-Mwcnt For High Precision Non-Enzymatic Glucose Sensing</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/11725</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.matchemphys.2020.123042</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, we report the synthesis and application of palladium-nickel nanoparticles decorated on functionalized-multiwall carbon nanotube Pd-Ni@f-MWCNT and employed as a sensitive non-enzymatic electrochemical glucose sensor. The composition and crystal structure was characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and Raman spectroscopy. The surface morphology of Pd-Ni@f-MWCNT was investigated by a transmission electron microscopy (TEM). The electrochemical response of the Pd-Ni@f-MWCNT to glucose was examined via the cyclic voltammetry. Results revealed that the prepared electrode exhibits high electrocatalytic activity for the oxidation of glucose into gluconolactone. The ampero-metric response of the Pd-Ni@f-MWCNT electrode to glucose was investigated at a potential of 0.5 V that demonstrated an extended linear range of from 0.01 to 1.4 mM, very low detection limit of 0.026 mu M, very high sensitivity at 71 mu A mM(-1) cm(-2) , as well as good reproducibility, high stability and applicability for the real sample analysis. The reliability of the developed sensor was verified by comparison with a commercially available glucometer. The obtained results indicate that Pd-Ni@f-MWCNT is a promising candidate for electrochemical glucose sensing.</description>
  </descriptions>
</resource>
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