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Synthesis of phthalocyanines crosswise-substituted with two alkylsulfanyl and two amino groups

Dabak, S; Bekaroglu, O


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  <dc:creator>Dabak, S</dc:creator>
  <dc:creator>Bekaroglu, O</dc:creator>
  <dc:date>1997-01-01</dc:date>
  <dc:description>Crosswise-substituted phthalocyanines (4, 4a-c) with two nitro and two dodecylsulfanyl groups are synthesized by a 2:2 condensation of 1,3-dihydro-1,3-diimino-6-(n-dodecylsulfanyl)isoiminoindolenine (2) with 6-nitro-1,3,3-trichloroisoindolenine (3) in the presence of sodium methoxide, hydroquinone and triethylamine. Nitro substituents are reduced to amines by sodium sulfide and condensation of the amine groups with ferrocenylaldehyde results in a new pc with two ferrocenylimino substituents, The novel compounds are characterized by UV/vis, mass and H-1-NMR spectroscopy.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/102459</dc:identifier>
  <dc:identifier>oai:zenodo.org:102459</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>NEW JOURNAL OF CHEMISTRY 21(2) 267-271</dc:source>
  <dc:title>Synthesis of phthalocyanines crosswise-substituted with two alkylsulfanyl and two amino groups</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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