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Synthesis of phthalocyanines crosswise-substituted with two alkylsulfanyl and two amino groups

Dabak, S; Bekaroglu, O


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{
  "URL": "https://aperta.ulakbim.gov.tr/record/102459", 
  "abstract": "Crosswise-substituted phthalocyanines (4, 4a-c) with two nitro and two dodecylsulfanyl groups are synthesized by a 2:2 condensation of 1,3-dihydro-1,3-diimino-6-(n-dodecylsulfanyl)isoiminoindolenine (2) with 6-nitro-1,3,3-trichloroisoindolenine (3) in the presence of sodium methoxide, hydroquinone and triethylamine. Nitro substituents are reduced to amines by sodium sulfide and condensation of the amine groups with ferrocenylaldehyde results in a new pc with two ferrocenylimino substituents, The novel compounds are characterized by UV/vis, mass and H-1-NMR spectroscopy.", 
  "author": [
    {
      "family": "Dabak", 
      "given": " S"
    }, 
    {
      "family": "Bekaroglu", 
      "given": " O"
    }
  ], 
  "container_title": "NEW JOURNAL OF CHEMISTRY", 
  "id": "102459", 
  "issue": "2", 
  "issued": {
    "date-parts": [
      [
        1997, 
        1, 
        1
      ]
    ]
  }, 
  "page": "267-271", 
  "title": "Synthesis of phthalocyanines crosswise-substituted with two alkylsulfanyl and two amino groups", 
  "type": "article-journal", 
  "volume": "21"
}
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