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Monodisperse CoFe2O4 nanoparticles supported on Vulcan XC-72: High performance electrode materials for lithium-air and lithium-ion batteries

Sener, Tansel; Kayhan, Emine; Sevim, Melike; Metin, Onder


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{
  "@context": "https://schema.org/", 
  "@id": 100427, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "TUBITAK, Energy Inst, Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkey", 
      "name": "Sener, Tansel"
    }, 
    {
      "@type": "Person", 
      "affiliation": "TUBITAK, Energy Inst, Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkey", 
      "name": "Kayhan, Emine"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Fac Sci & Educ, Dept Chem, TR-25240 Erzurum, Turkey", 
      "name": "Sevim, Melike"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Fac Sci & Educ, Dept Chem, TR-25240 Erzurum, Turkey", 
      "name": "Metin, Onder"
    }
  ], 
  "datePublished": "2015-01-01", 
  "description": "Addressed herein is the preparation and the electrode performance of monodisperse CoFe2O4 nanoparticles (NPs) supported on Vulcan XC-72 for the Lithium-air battery (LAB) and Lithium-ion battery (LIB). Monodisperse CoFe2O4 NPs were synthesized by the thermal decomposition of cobalt(II) acetylacetonate and iron(III) acetylacetonate in oleylamine and oleic acid in the presence of 1,2-tetradecanediol and benzyl ether. As-prepared CoFe2O4 NPs with a particle size of 11 nm were then supported on Vulcan XC-72 (Vulcan-CoFe2O4) at different theoretical loadings (20, 40 and 60 wt % CoFe2O4 NPs) by using the simple liquid phase self assembly method. CoFe2O4 NPs dispersed on Vulcan-CoFe2O4 composites were characterized by transmission electron microscopy (TEM), powder X-ray diffraction (PXRD) and atomic absorption spectroscopy (AAS). The MS analyses indicated that the Vulcan-CoFe2O4 composites with different loadings were included 3.7, 8.1 and 16.4 wt % CoFe2O4 on the metal basis. The electrode performance of Vulcan-CoFe2O4 composites were evaluated as the anode active material for LIB and cathode active material for LABs by performing the galvanostatic charge-discharge tests. The highest discharge capacity for both LAB (7510 mAh g((Vulcan+CoFe2O4))(-1); 13380 mAh g(CoFe2O4)(-1) @ 0.1C) and LIB (863 mAh g((Vulcan+CoFe2O4))(-1); 9330 mAh g(CoFe2O4)(-1)@ 0.1C) was investigated with 16.4 wt % CoFe2O4. (c) 2015 Elsevier B.V. All rights reserved.", 
  "headline": "Monodisperse CoFe2O4 nanoparticles supported on Vulcan XC-72: High performance electrode materials for lithium-air and lithium-ion batteries", 
  "identifier": 100427, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Monodisperse CoFe2O4 nanoparticles supported on Vulcan XC-72: High performance electrode materials for lithium-air and lithium-ion batteries", 
  "url": "https://aperta.ulakbim.gov.tr/record/100427"
}
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