Dergi makalesi Açık Erişim
Sener, Tansel; Kayhan, Emine; Sevim, Melike; Metin, Onder
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/100427</identifier> <creators> <creator> <creatorName>Sener, Tansel</creatorName> <givenName>Tansel</givenName> <familyName>Sener</familyName> <affiliation>TUBITAK, Energy Inst, Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkey</affiliation> </creator> <creator> <creatorName>Kayhan, Emine</creatorName> <givenName>Emine</givenName> <familyName>Kayhan</familyName> <affiliation>TUBITAK, Energy Inst, Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkey</affiliation> </creator> <creator> <creatorName>Sevim, Melike</creatorName> <givenName>Melike</givenName> <familyName>Sevim</familyName> <affiliation>Ataturk Univ, Fac Sci & Educ, Dept Chem, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Metin, Onder</creatorName> <givenName>Onder</givenName> <familyName>Metin</familyName> <affiliation>Ataturk Univ, Fac Sci & Educ, Dept Chem, TR-25240 Erzurum, Turkey</affiliation> </creator> </creators> <titles> <title>Monodisperse Cofe2O4 Nanoparticles Supported On Vulcan Xc-72: High Performance Electrode Materials For Lithium-Air And Lithium-Ion Batteries</title> </titles> <publisher>Aperta</publisher> <publicationYear>2015</publicationYear> <dates> <date dateType="Issued">2015-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/100427</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.jpowsour.2015.04.120</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">Addressed herein is the preparation and the electrode performance of monodisperse CoFe2O4 nanoparticles (NPs) supported on Vulcan XC-72 for the Lithium-air battery (LAB) and Lithium-ion battery (LIB). Monodisperse CoFe2O4 NPs were synthesized by the thermal decomposition of cobalt(II) acetylacetonate and iron(III) acetylacetonate in oleylamine and oleic acid in the presence of 1,2-tetradecanediol and benzyl ether. As-prepared CoFe2O4 NPs with a particle size of 11 nm were then supported on Vulcan XC-72 (Vulcan-CoFe2O4) at different theoretical loadings (20, 40 and 60 wt % CoFe2O4 NPs) by using the simple liquid phase self assembly method. CoFe2O4 NPs dispersed on Vulcan-CoFe2O4 composites were characterized by transmission electron microscopy (TEM), powder X-ray diffraction (PXRD) and atomic absorption spectroscopy (AAS). The MS analyses indicated that the Vulcan-CoFe2O4 composites with different loadings were included 3.7, 8.1 and 16.4 wt % CoFe2O4 on the metal basis. The electrode performance of Vulcan-CoFe2O4 composites were evaluated as the anode active material for LIB and cathode active material for LABs by performing the galvanostatic charge-discharge tests. The highest discharge capacity for both LAB (7510 mAh g((Vulcan+CoFe2O4))(-1); 13380 mAh g(CoFe2O4)(-1) @ 0.1C) and LIB (863 mAh g((Vulcan+CoFe2O4))(-1); 9330 mAh g(CoFe2O4)(-1)@ 0.1C) was investigated with 16.4 wt % CoFe2O4. (c) 2015 Elsevier B.V. All rights reserved.</description> </descriptions> </resource>
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