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Detoxification of waste hand paper towel hydrolysate by activated carbon adsorption

Onaran, G.; Gurel, L.; Argun, H.


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{
  "DOI": "10.1007/s13762-019-02499-w", 
  "abstract": "This study presents 5-hydroxymethylfurfural removal from waste hand paper hydrolysate using activated carbon adsorption. In this context, the effects of adsorbent dosage, initial 5-hydroxymethylfurfural concentration, temperature, and agitation speed on 5-hydroxymethylfurfural adsorption were investigated. Moreover, isotherm and kinetic evaluations were performed using Langmuir, Freundlich, and Temkin models. The experimental data were correlated with zero, first, pseudo-first, and Weber-Morris intraparticle diffusion models. The toxicity of 5-hydroxymethylfurfural was determined using the resazurin reduction assay, and the EC50 of 5-hydroxymethylfurfural in the hydrolysate was found as 192 mg/L. Most convenient 5-hydroxymethylfurfural adsorption was obtained at 5 g/L AC dosage, 40 degrees C and 150 rpm agitation speed. The highest 5-hydroxymethylfurfural removal efficiency was 92% at 7 g/L AC dosage. The adsorption data fitted best with the Langmuir isotherm model with a maximum uptake capacity of 70.92 mg/g (R-2: 0.96). The zero-order reaction kinetic model was the most suitable one among the others inspected. It was determined that intraparticle diffusion was not the rate-limiting step. This study showed that waste hand paper hydrolysate can effectively be detoxified by activated carbon adsorption.", 
  "author": [
    {
      "family": "Onaran", 
      "given": " G."
    }, 
    {
      "family": "Gurel", 
      "given": " L."
    }, 
    {
      "family": "Argun", 
      "given": " H."
    }
  ], 
  "container_title": "INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY", 
  "id": "9493", 
  "issue": "2", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "page": "799-808", 
  "title": "Detoxification of waste hand paper towel hydrolysate by activated carbon adsorption", 
  "type": "article-journal", 
  "volume": "17"
}
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