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Ultralow Pt loading on CVD graphene for acid electrolytes and PEM fuel cells

Yazici, M. Suha; Azder, M. Akif; Salihoglu, Omer; San, F. Gul Boyaci


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{
  "@context": "https://schema.org/", 
  "@id": 93139, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Marmara Res Ctr, Energy Inst, PK 21, TR-41470 Gebze, Turkey", 
      "name": "Yazici, M. Suha"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Marmara Res Ctr, Energy Inst, PK 21, TR-41470 Gebze, Turkey", 
      "name": "Azder, M. Akif"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Marmara Res Ctr, Energy Inst, PK 21, TR-41470 Gebze, Turkey", 
      "name": "Salihoglu, Omer"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Marmara Res Ctr, Energy Inst, PK 21, TR-41470 Gebze, Turkey", 
      "name": "San, F. Gul Boyaci"
    }
  ], 
  "datePublished": "2018-01-01", 
  "description": "Continuous-phase, porous graphene was produced by CVD process and tested for suitability as catalyst and catalyst support for polymer electrolyte membrane (PEM) fuel cells. N-doping of CVD graphene was carried by NH3 gas flown over graphene for a given time. Ultralow Pt was sputter deposited onto porous, continuous phase N-doped graphene. Oxygen reduction reaction (ORR) activity by Rotating Disc Electrode (RDE) in 0,1 M HClO4 electrolyte and PEM fuel cell performance were measured. N-doping and thicker Pt sputtering increases reduction current in RDE measurements. Sputter deposition of 1 nm and 10 nm Pt on CVD graphene (2.1 and 21.45 mu gPt/cm(2) loading) has shown orders of magnitude increase in current compare to only-graphene samples. In fuel cell testing, sputter deposited Pt layer of 10 nm has provided 2.5 A/mgPt at 0.5 V polarization while 1 nm samples shows 15 A/mgPt performance at the same voltage. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", 
  "headline": "Ultralow Pt loading on CVD graphene for acid electrolytes and PEM fuel cells", 
  "identifier": 93139, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Ultralow Pt loading on CVD graphene for acid electrolytes and PEM fuel cells", 
  "url": "https://aperta.ulakbim.gov.tr/record/93139"
}
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