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Comparative studies of photophysical and photochemical properties of solketal substituted platinum(II) and zinc(II) phthalocyanine sets

Zorlu, Yunus; Dumoulin, Fabienne; Durmus, Mahmut; Ahsen, Vefa


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/92609</identifier>
  <creators>
    <creator>
      <creatorName>Zorlu, Yunus</creatorName>
      <givenName>Yunus</givenName>
      <familyName>Zorlu</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dumoulin, Fabienne</creatorName>
      <givenName>Fabienne</givenName>
      <familyName>Dumoulin</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Durmus, Mahmut</creatorName>
      <givenName>Mahmut</givenName>
      <familyName>Durmus</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ahsen, Vefa</creatorName>
      <givenName>Vefa</givenName>
      <familyName>Ahsen</familyName>
    </creator>
  </creators>
  <titles>
    <title>Comparative Studies Of Photophysical And Photochemical Properties Of Solketal Substituted Platinum(Ii) And Zinc(Ii) Phthalocyanine Sets</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/92609</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.tet.2010.02.079</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A complete set of platinum(II) solketal substituted phthalocyanines has been synthesized and characterized. To evaluate their potential as Type II photosensitizers for photodynamic therapy, comparative studies of their photophysical and photochemical properties with analogous zinc(II) series have been achieved: electronic absorption, fluorescence quantum yields, lifetimes, and fluorescence quenching by benzoquinone, as well as singlet oxygen generation and photodegradation. It appears that platinum(II) phthalocyanines are worth being used as Type II photosensitizers, as they exhibit good singlet oxygen generation and appropriate photodegradation. (C) 2010 Elsevier Ltd. All rights reserved.</description>
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