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Liquid crystalline octasubstituted lead(II) phthalocyanines: effects of alkoxy and alkylthio substituents on film alignment and electrical properties

Tuncel, Sinem; Banimuslem, Hikmat A. J.; Durmus, Mahmut; Gurek, Ayse Gul; Ahsen, Vefa; Basova, Tamara V.; Hassan, Aseel K.


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        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
        "name": "Tuncel, Sinem"
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        "affiliation": "Sheffield Hallam Univ, Fac Arts Comp Engn & Sci, Sheffield S1 2NU, S Yorkshire, England", 
        "name": "Banimuslem, Hikmat A. J."
      }, 
      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
        "name": "Durmus, Mahmut"
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      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
        "name": "Gurek, Ayse Gul"
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      {
        "name": "Ahsen, Vefa"
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        "affiliation": "Nikolaev Inst Inorgan Chem SB RAS, Novosibirsk 630090, Russia", 
        "name": "Basova, Tamara V."
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      {
        "affiliation": "Sheffield Hallam Univ, Fac Arts Comp Engn & Sci, Sheffield S1 2NU, S Yorkshire, England", 
        "name": "Hassan, Aseel K."
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    "description": "Octasubstituted lead(II) phthalocyanines containing alkylthio- and alkoxy-groups in peripheral positions have been synthesized and characterized using H-1 and C-13 NMR, UV-Vis, IR and mass spectroscopies as well as elemental analysis. The mesogenic properties of the octasubstituted lead(II) phthalocyanines have been investigated by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction. The sandwich structures ITO/PbPc/In were prepared to investigate the J(V) characteristics of thin films of these molecules. The dissimilar behavior of the films before and after heat-treatment is expected to result in changing the alignment inside the columnar stacking of the molecules in the films.", 
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