1 Ocak 2013 Dergi makalesi Açık Erişim

Avci, Ercan; Mazman, Muhsin; Uzun, Davut; Bicer, Emre; Sener, Tansel

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  <dc:creator>Avci, Ercan</dc:creator>
  <dc:creator>Mazman, Muhsin</dc:creator>
  <dc:creator>Uzun, Davut</dc:creator>
  <dc:creator>Bicer, Emre</dc:creator>
  <dc:creator>Sener, Tansel</dc:creator>
  <dc:date>2013-01-01</dc:date>
  <dc:description>A facile and efficient solid state synthesis of carbon and nitrogen coated lithium iron phosphate (LiFePO4/CN) cathode material is achieved via polymer-pyrolysis method using polyaniline-chloride (PANI-CI). The current investigation is comparatively analyzed with the results of the composite of LiFePO4/C (LFP/C) synthesized using sucrose as carbon precursor. The optimized LiFePO4/CN (LFP/CN) composite is synthesized at 700 degrees C using 10 wt.% PANI-CI. The composite exhibits remarkable improvement in capacity, cyclability and rate capability compared to those of LFP/C. The specific discharge capacities as high as 164 mAh g(-1) (theoretical capacity: 170 mAh g(-1)) at 0.1 C and 100 mAh g(-1) at 10 C rates were achieved with LFP/CN. In addition, the composite exhibits a long-term cycling stability with the capacity loss of only 10% after 1000 cycles. PANI-CI shifts the size distribution of the composite to nanometer scale (approximately 150 nm), however the addition of sucrose does not have such an effect. LFP/CN contains 1.6 wt.% nitrogen and 15.8 wt.% carbon. LFP particles are mostly coated with a few nanometers thick C-N layer forming a core-shell structure. The possible crosslinking mechanism of PANI-Cl upon pyrolysis on size reduction and formation of uniform carbon/nitrogen coating on LFP are also discussed. (C) 2013 Elsevier B.V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/89309</dc:identifier>
  <dc:identifier>oai:zenodo.org:89309</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF POWER SOURCES 240 328-337</dc:source>
  <dc:title>High performance LiFePO4/CN cathode material promoted by polyaniline as carbon-nitrogen precursor</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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