1 Ocak 2020 Dergi makalesi Açık Erişim

Ozkose, Umut Ugur; Yilmaz, Ozgur; Alpturk, Onur

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/89163</identifier>
  <creators>
    <creator>
      <creatorName>Ozkose, Umut Ugur</creatorName>
      <givenName>Umut Ugur</givenName>
      <familyName>Ozkose</familyName>
    </creator>
    <creator>
      <creatorName>Yilmaz, Ozgur</creatorName>
      <givenName>Ozgur</givenName>
      <familyName>Yilmaz</familyName>
      <affiliation>TUBITAK, Mat Inst, Marmara Res Ctr, TR-41470 Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Alpturk, Onur</creatorName>
      <givenName>Onur</givenName>
      <familyName>Alpturk</familyName>
      <affiliation>Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of Poly(2-Ethyl-2-Oxazoline)-B-Poly(Epsilon-Caprolactone) Conjugates By A New Modular Strategy</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/89163</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1007/s00289-019-03038-w</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Amphiphilic block copolymers where hydrophobicity and hydrophilicity coincide are essential building blocks for many supramolecular systems. By this time, polyethylene glycol (PEG) has been a conventional choice to constitute hydrophilicity; however, it suffers from certain drawbacks, severely limiting its use in these compounds. To date, one potential modality to overcome this complication is to utilize poly(2-ethyl-2-oxazoline) (PEtOx) instead, given that this also-hydrophilic polymer is very comparable to PEG, in many ways. In this regard, amphiphilic block copolymers harboring PEtOx and synthetic approaches to access these polymeric materials have been documented in the literature. Within this scope, we crafted a modular approach for the synthesis of poly(2-ethyl-2-oxazoline)-b-poly(epsilon-caprolactone) to govern its molecular structure. Herein, we extend this work and report a novel poly(2-ethyl-2-oxazoline)-b-poly(epsilon-caprolactone) derivative with electrophilic moiety on terminal position. We believe that this novel design could lead up to expeditious synthesis of block copolymer-biomolecule conjugates, which are of paramount significance for many applications.</description>
  </descriptions>
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