1 Ocak 2020 Dergi makalesi Açık Erişim

Ozkose, U. U.; Gulyuz, S.; Oz, U. C.; Tasdelen, M. A.; Alpturk, O.; Bozkir, A.; Yilmaz, O.

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    <subfield code="a">Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(epsilon-caprolactone) (PEtOx-b-PCL) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions</subfield>
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    <subfield code="a">Amphiphilic block copolymers are known to self-assemble into various morphologies, including ellipsoids, tubular structures, toroids, vesicles, micellar structures. In this paper, we discuss the synthesis of copolymeric nanostructures (CNs) using poly(2-ethyl-2-oxazoline)-block-poly(epsilon-caprolactone) (PEtOx-b-PCL) amphiphilic block copolymers. Our data indicate that - varying the molecular weight and the number of repeating units dictate the nature of morphology. That is, the formation of self-assembled morphologies from ellipsoid to rod-like architectures are observed in aqueous solution, depending on the mass ratio of the hydrophilic block (f(PEtOx)). To best of our knowledge, this is the first report on the morphological transitions of PEtOx-b-PCL amphiphilic block copolymer-based CNs with different f(PEtOx)) values in the literature.</subfield>
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    <subfield code="a">Gulyuz, S.</subfield>
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    <subfield code="u">Ankara Univ, Fac Pharm, Dept Pharmaceut Technol, TR-06560 Ankara, Turkey</subfield>
    <subfield code="a">Oz, U. C.</subfield>
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    <subfield code="u">Yalova Univ, Fac Engn, Dept Polymer Engn, TR-77200 Yalova, Turkey</subfield>
    <subfield code="a">Tasdelen, M. A.</subfield>
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    <subfield code="u">Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, TR-34469 Istanbul, Turkey</subfield>
    <subfield code="a">Alpturk, O.</subfield>
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