1 Ocak 2012 Dergi makalesi Açık Erişim

Siga, Fatma; Temel, Hamdi; Aydemir, Murat; Ocak, Yusuf Selim; Pasa, Salih; Baysal, Akin

Citation Style Language JSON

{
  "DOI": "10.1016/j.apcata.2012.09.048", 
  "abstract": "A set of three new polymer-anchored palladium(II) Schiff base catalysts have been synthesized, characterized and their catalytic activity was investigated in the Suzuki cross-coupling reaction between aryl halides and arylboronic acid in the presence of Cs2CO3 as a base. They show excellent catalytic activity in coupling of aryl bromides or aryl iodide with phenylboronic acid under the optimized reaction conditions in water. Polymer-anchored Pd(II) complexes provided turnover frequency of 29,700 or 58,200 h(-1) in Suzuki coupling reactions of phenylboronic acid with p-bromoacetophenone or p-iodobenzene, respectively, which are the highest values ever reported for the Suzuki coupling reactions in water as sole solvent. The catalyst 1 could be used for 15 reaction cycles in the Suzuki coupling of p-acetobromobenzene at 100 degrees C with no loss of catalytic activity. (C) 2012 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Siga", 
      "given": " Fatma"
    }, 
    {
      "family": "Temel", 
      "given": " Hamdi"
    }, 
    {
      "family": "Aydemir", 
      "given": " Murat"
    }, 
    {
      "family": "Ocak", 
      "given": " Yusuf Selim"
    }, 
    {
      "family": "Pasa", 
      "given": " Salih"
    }, 
    {
      "family": "Baysal", 
      "given": " Akin"
    }
  ], 
  "container_title": "APPLIED CATALYSIS A-GENERAL", 
  "id": "88929", 
  "issued": {
    "date-parts": [
      [
        2012, 
        1, 
        1
      ]
    ]
  }, 
  "page": "172-182", 
  "title": "Superb efficient and recycle polymer-anchored systems for palladium catalyzed Suzuki cross-coupling reactions in water", 
  "type": "article-journal", 
  "volume": "449"
}