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A highly aromatic and sulfonated ionomer for high elastic modulus ionic polymer membrane micro-actuators

Hatipoglu, Gokhan; Liu, Yang; Zhao, Ran; Yoonessi, Mitra; Tigelaar, Dean M.; Tadigadapa, Srinivas; Zhang, Q. M.


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{
  "DOI": "10.1088/0964-1726/21/5/055015", 
  "abstract": "A high modulus, sulfonated ionomer synthesized from 4,6-bis(4-hydroxyphenyl)-N,N-diphenyl-1,3,5-triazin-2-amine and 4,4'-biphenol with bis(4-fluorophenyl)sulfone (DPA-PS:BP) is investigated for ionic polymer actuators. The uniqueness of DPA-PS: BP is that it can have a high ionic liquid (IL) uptake and consequently generates a high intrinsic strain response, which is >1.1% under 1.6 V while maintaining a high elastic modulus (i.e. 600 MPa for 65 vol% IL uptake). Moreover, such a high modulus of the active ionomer, originating from the highly aromatic backbone and side-chain-free structure, allows for the fabrication of free-standing thin film micro-actuators (down to 5 mu m thickness) via the solution cast method and focused-ion-beam milling, which exhibits a much higher bending actuation, i.e. 43 mu m tip displacement and 180 kPa blocking stress for a 200 mu m long and 5 mu m thick cantilever actuator, compared with the ionic actuators based on traditional ionomers such as Nafion, which has a much lower elastic modulus (50 MPa) and actuation strain.", 
  "author": [
    {
      "family": "Hatipoglu", 
      "given": " Gokhan"
    }, 
    {
      "family": "Liu", 
      "given": " Yang"
    }, 
    {
      "family": "Zhao", 
      "given": " Ran"
    }, 
    {
      "family": "Yoonessi", 
      "given": " Mitra"
    }, 
    {
      "family": "Tigelaar", 
      "given": " Dean M."
    }, 
    {
      "family": "Tadigadapa", 
      "given": " Srinivas"
    }, 
    {
      "family": "Zhang", 
      "given": " Q. M."
    }
  ], 
  "container_title": "SMART MATERIALS AND STRUCTURES", 
  "id": "88455", 
  "issue": "5", 
  "issued": {
    "date-parts": [
      [
        2012, 
        1, 
        1
      ]
    ]
  }, 
  "title": "A highly aromatic and sulfonated ionomer for high elastic modulus ionic polymer membrane micro-actuators", 
  "type": "article-journal", 
  "volume": "21"
}
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