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Interaction of Cr3+ with Silica Gel at the Aqueous Interface Using Fluorescence in Sodium Dodecyl Sulfate Micelles and Confocal Fluorescence Microscopy

Idrees, Muhammad; Silva, Marcelo; Silva, Alessandra F.; Zimmermann, Lizandra M.; Bruch, Jociane; Mendonca, Caio O.; Almerindo, Gizelle I.; Nome, Rene A.; Atvars, Teresa D. Z.; Fiedler, Haidi D.; Nome, Faruk


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  "@id": 86721, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Idrees, Muhammad"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Silva, Marcelo"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Silva, Alessandra F."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Zimmermann, Lizandra M."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Bruch, Jociane"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Mendonca, Caio O."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Almerindo, Gizelle I."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Estadual Campinas, Inst Chem, BR-13084824 Campinas, SP, Brazil", 
      "name": "Nome, Rene A."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Estadual Campinas, Inst Chem, BR-13084824 Campinas, SP, Brazil", 
      "name": "Atvars, Teresa D. Z."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Fiedler, Haidi D."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Fed Santa Catarina, Dept Quim, Natl Inst Sci & Technol Catalysis, BR-88040900 Florianopolis, SC, Brazil", 
      "name": "Nome, Faruk"
    }
  ], 
  "datePublished": "2012-01-01", 
  "description": "Chemical composition and species distribution in clay surfaces are key factors which control sorption and desorption processes of Cr3+ between sediment and water. Adsorption of Cr3+ on silica gel has been studied by following the quenching of naphthalene fluorescence in aqueous sodium dodecyl sulfate (SDS) micelles, which concentrate naphthalene and Cr3+ in the micellar surface. Adsorption for pH <= 5 follows a Langmuir model, and experimental data fitting is successfully described by a model based on discrete sites on the surface with variable charge as a function of pH. Probably the mechanism of Cr3+ adsorption at the silica gel surface is predominantly electrostatic, with outer-sphere complexation and ion exchange with adsorbed H+ ions. Confocal laser-scanning fluorescence microscopy measurements reveal the Cr3+ spatial distribution in three dimensions. Specifically, both images and spectra measured with confocal microscopy indicate that Cr3+ is distributed across the entire particle, not just adsorption at the surface.", 
  "headline": "Interaction of Cr3+ with Silica Gel at the Aqueous Interface Using Fluorescence in Sodium Dodecyl Sulfate Micelles and Confocal Fluorescence Microscopy", 
  "identifier": 86721, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Interaction of Cr3+ with Silica Gel at the Aqueous Interface Using Fluorescence in Sodium Dodecyl Sulfate Micelles and Confocal Fluorescence Microscopy", 
  "url": "https://aperta.ulakbim.gov.tr/record/86721"
}
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