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Butylbis(dimethylglyoximato-kappa N-2,N ')(pyridine-kappa N)cobalt(III)

Kumar, Sarvendra; Thapa, Suresh


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/83623</identifier>
  <creators>
    <creator>
      <creatorName>Kumar, Sarvendra</creatorName>
      <givenName>Sarvendra</givenName>
      <familyName>Kumar</familyName>
      <affiliation>Univ Buenos Aires, DQIAQF INQUIMAE, Buenos Aires, DF, Argentina</affiliation>
    </creator>
    <creator>
      <creatorName>Thapa, Suresh</creatorName>
      <givenName>Suresh</givenName>
      <familyName>Thapa</familyName>
      <affiliation>Purbanchal Univ, Fac Sci &amp; Technol, Biratnagar, Nepal</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Butylbis(Dimethylglyoximato-Kappa N-2,N ')(Pyridine-Kappa N)Cobalt(Iii)</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2012</publicationYear>
  <dates>
    <date dateType="Issued">2012-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/83623</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1107/S1600536812000967</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In the title compound, [Co(C4H9)(C4H7N2O2)(2)(C5H5N)], which was prepared as a model complex of vitamin B-12, the Co-III atom is coordinated by a butyl group, a pyridine and two N,N'-bidentate dimethylglyoximate ligands in a distorted octahedral geometry. The bis-chelating dimethylglyoximate ligands, which occupy equatorial sites, are linked by strong intramolecular O-H center dot center dot center dot O hydrogen bonds.</description>
  </descriptions>
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